Sodium pyrosilicate

Sodium pyrosilicate

Names
Other names hexasodium diorthosilicate
Identifiers
CAS Number	15593-82-5 N
3D model (JSmol)	Interactive image
EC Number	239-671-1
PubChem CID	61803
UNII	VNJ6H8MB6Z N
InChI InChI=1S/6Na.O7Si2/c;;;;;;1-8(2,3)7-9(4,5)6/q6*+1;-6 Key: PMYUVOOOQDGQNW-UHFFFAOYSA-N
SMILES [Si](O[Si]([O-])([O-])[O-])([O-])([O-])[O-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+]
Properties
Chemical formula	Na6O7Si2
Molar mass	306.102 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N (what is YN ?) Infobox references

Sodium pyrosilicate is the chemical compound Na
₆Si
₂O
₇. It is one of the sodium silicates, specifically a pyrosilicate, formally a salt of the unstable pyrosilicic acid H
₆Si
₂O
₇.

Structure

The anhydrous solid has the triclinic crystal structure, with space group P1 (a = 5.8007(8) Å, b = 11.5811(15) Å, c = 23.157(3) Å, α = 89.709(10)°, β = 88.915(11)°, γ = 89.004(11)°, V = 1555.1(4) ų, Z = 8, Dx = 2.615 g·cm⁻³, μ(Mo‐Kα) = 7.94 cm⁻¹). The Si
₂O⁶⁺
₇ anions are arranged in layers parallel to the (100) plane, with the sodium cations distributed in 24 distinct crystallographic positions, coordinated by 4 to 6 near oxygen atoms. Some of the 4-coordinated sodium atoms can be interpreted as parallel columns of edge-sharing NaO
₄ tetrahedra. The columnar arrangement forms tunnels that house the remaining sodium cations. Twinning at a microscopic scale simulates a much larger monoclinic C centered lattice (V′ = 6220 ų, Z = 32).

See also

• Sodium metasilicate, Na
  ₂SiO
  ₃
• Sodium orthosilicate, Na
  ₄SiO
  ₄