Jump to content

Molozonide

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by InternetArchiveBot (talk | contribs) at 08:43, 20 March 2020 (Bluelink 1 book for verifiability (goog)) #IABot (v2.0) (GreenC bot). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

General chemical structure of molozonides

A molozonide (or "molecular ozonide") is a 1,2,3-trioxolane, which can also be thought of a cyclic dialkyl trioxidane.[1] Molozonides are formed by cycloaddition of ozone and an alkene during ozonolysis, as a transient intermediate which quickly rearranges to give the ozonide (1,2,4-trioxolane), the relatively stable product generated immediately prior to reductive or oxidative cleavage to form alcohols, carbonyl compounds, or derivatives thereof.[2]

References

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "molozonides". doi:10.1351/goldbook.M04004
  2. ^ McMurry, John (2004). Organic Chemistry, 6th ed. Belmont: Brooks/Cole. p. 225. ISBN 978-0-534-38999-4.