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Skaergaardite

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Skaergaardite
General
CategoryPlatinum group mineral
Formula
(repeating unit)
PdCu
Strunz classification1.AG.30
Crystal systemCubic
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupPm3m
Unit cella = 3.0014(2) Å
V = 27.0378 Å3, Z = 1
Identification
ColorSteel grey with a bronze tint
Crystal habitOccurs as droplets, equant grains with rounded outlines, subhedral to euhedral crystals, and as irregular grains that vary in size from 2 to 75 micrometers, averaging 22 micrometers.
TenacitySectile
Mohs scale hardness4 to 5
LusterMetallic
StreakBlack
DiaphaneityOpaque
Specific gravity10.64
Optical propertiesIsotropic; no discernible internal reflections; color varying from bright creamy white to bright white.
PleochroismNon-pleochroic
Other characteristicsTypically found in composite microglobules in tholeitic gabbro.
References[1][2][3]

Skaergaardite is an intermetallic platinum group mineral with the general chemical formula PdCu. The mineral is named after its discovery location: the Skaergaard intrusion, Kangerdlugssuaq area, East Greenland. The mineral name was approved by the International Mineralogical Association in 2003. The mineral has also been reported in the Duluth intrusion in Minnesota and the Rum layered intrusion in Scotland.[2]

Occurrence

Skaergaardite is associated with igneous intrusions containing well-preserved, oxide-rich, tholeiitic gabbro. It is found as inclusions in titanian magnetite, ilmenite, pyroxenes, and plagioclase. Skaergaardite can occur as an inclusion by itself, but is more commonly found in composite microglobule inclusions of copper iron sulfide minerals and other precious metal bearing minerals.[2]

Crystallography and symmetry

The crystallography of skaergaardite was determined using x-ray powder diffraction data. It has an isometric (cubic) crystal system and a hexoctahedral crystal class (Hermann–Mauguin notation: 4/m32/m). Skaergaardite can appear in various forms including: droplets; cubic grains with rounded outlines; euhedral to subhedral grains; and irregular grains or aggregates.[1][2]

Optical properties

When viewed under a microscope in plane polarized light, skaergaardite appears to be bright creamy white (in the presence of bornite or chalcopyrite) or bright white (in the presence of digenite or chalcocite). When the mineral is rotated on the microscope stage its color does not change, indicating that it is non-pleochroic.

Under crossed polar light, skaergaardite appears completely dark no matter the direction the stage is rotated, indicating that the mineral is isotropic. As skaergaardite is isotropic, it is also non-birefringent.[2][4]

Importance

Skaergaardite contains palladium (Pd), one of the six platinum group metals (PGM) that are some of the rarest elements on earth.[5] With the cost of palladium expected to increase as demand becomes greater, Skaergaardite could begin to be mined for its valuable palladium resources.[6]

The Skaergaard intrusion is the only known source of skaergaardite large enough to be mined. Skaergaardite is the most common PGM mineral in the intrusion, making up over 90% of all the PGM observed.[2] The most mineral-rich layer of the intrusion could contain over 1000 tons of skaergaardite. In addition to palladium: gold, platinum, and other precious metals have been found in the intrusion.[6] Interest has been increasing for an underground mine in the Skaergaard intrusion. A pre-feasibility study is currently under way and is scheduled for completion by December 2011.[7]

References

  1. ^ a b Ralph, J., and Chau, I., "Skaergaardite." Mindat.org. <http://www.mindat.org/min-26980.html>. Accessed 30 September 2010.
  2. ^ a b c d e f Rudashevsky, N.S., McDonald, A.M., Cabri, L.J., Nielsen, T.F.D., Stanley, C.J., Kretzer, Yu. L., and Rudashevsky, V.N. (2004) Skaergaardite, PdCu, a new platinum-group intermetallic mineral from the Skaergaard intrusion, Greenland. Mineralogical Magazine, 68, 615-632.
  3. ^ Webmineral data
  4. ^ Klein, C., and Dutrow, B. (2007) The 23rd Edition of the Manual of Mineral Science. John Wiley and Sons, Inc. Hoboken, New Jersey, U.S.A.
  5. ^ Powell, D, 2000, "Platinum Group." Mineral Information Institute. <http://www.mii.org/Minerals/photoplat.html>. Accessed 23 November 2010.
  6. ^ a b Brooks, K. (2005) The Skaergaard intrusion: from icon to precious metal deposit. Geology Today, 21, 218-221.
  7. ^ Platina Resources Limited, 7 October 2009, "Skaergaard Gold-PGM Project Moves To Next Stage Following Positive Scoping Study Review." <http://us-cdn.creamermedia.co.za/assets/articles/attachments/23878_pgm_071009.pdf>. Accessed 23 November 2010.