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Acetyl bromide

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Acetyl bromide[1]
Structural formula of acetyl bromide
Structural formula of acetyl bromide
Ball-and-stick model of acetyl bromide
Ball-and-stick model of acetyl bromide
Names
IUPAC name
Acetyl bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.329 Edit this at Wikidata
  • InChI=1S/C2H3BrO/c1-2(3)4/h1H3 checkY
    Key: FXXACINHVKSMDR-UHFFFAOYSA-N checkY
  • InChI=1/C2H3BrO/c1-2(3)4/h1H3
    Key: FXXACINHVKSMDR-UHFFFAOYAZ
  • CC(=O)Br
  • BrC(=O)C
Properties
C2H3BrO
Molar mass 122.95 g/mol
Density 1.663 g/mL
Melting point −96 °C (−141 °F; 177 K)
Boiling point 75-77 °C
Hazards
Flash point 110 °C (230 °F; 383 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Acetyl bromide is an acyl bromide compound. As is expected, it may be prepared by reaction between phosphorus tribromide and acetic acid:[2]

3 CH3COOH + PBr3 → 3 CH3COBr + H3PO3

References

  1. ^ Acetyl bromide at Sigma-Aldrich
  2. ^ Theodore M. Burton and Ed. F. Degering (1940). "The Preparation of Acetyl Bromide". J. Am. Chem. Soc. 62: 227. doi:10.1021/ja01858a502.