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Allylamine

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Allylamine
Names
IUPAC name
3-Amino-prop-1-ene
Other names
3-aminopropene, 3-aminopropylene, monoallylamine, 2-propenamine, 2-propen-1-amine, allyl amine
Identifiers
3D model (JSmol)
ECHA InfoCard 100.003.150 Edit this at Wikidata
RTECS number
  • BA5425000
  • C=CCN
Properties
C3H7N
Molar mass 57.096 g·mol−1
Appearance colorless liquid
Density 0.7630 g/cm3, liquid
Melting point -88 °C
Boiling point 55-58 °C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Lachrymatory
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability (yellow): no hazard codeSpecial hazards (white): no code
4
3
Flash point -28 °C
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Allylamine is an organic compound with the formula C3H5NH2. This colourless liquid is the simplest stable unsaturated amine. It can be prepared by hydrolysis of allyl isothiocyanate.[1] It behaves as a typical amine.[2]

Reactions

Polymerization can be used to prepare the homopolymer (poly(allylamine)) or copolymers.

Safety

Allyl amine is highly toxic and is a lacrymator.

References

  1. ^ M. T. Leffler (1943). "Allylamine". Organic Syntheses; Collected Volumes, vol. 2, p. 24.
  2. ^ Henk de Koning, W. Nico Speckamp, "Allylamine" in Encyclopedia of Reagents for Organic Synthesis, 2001 John Wiley & Sons, Weinheim. doi:10.1002/047084289X.ra043 Article Online Posting Date: April 15, 2001