Aluminium formate

Aluminium formate
Names
	IUPAC name Aluminium triformate
Identifiers
CAS Number	7360-53-4 ;
3D model (JSmol)	Interactive image;
ChemSpider	56385;
ECHA InfoCard	100.028.089
PubChem CID	62632;
UNII	0D34IG724V ;
CompTox Dashboard (EPA)	DTXSID1044724 ;
	InChI InChI=1S/3CH2O2.Al/c32-1-3;/h31H,(H,2,3);/q;;;+3/p-3 Key: MJWPFSQVORELDX-UHFFFAOYSA-K; InChI=1/3CH2O2.Al/c32-1-3;/h31H,(H,2,3);/q;;;+3/p-3 Key: MJWPFSQVORELDX-DFZHHIFOAF;
	SMILES [Al+3].[O-]C=O.[O-]C=O.[O-]C=O;
Properties
Chemical formula	C3H3AlO6
Molar mass	162.033 g·mol−1
Appearance	White powder
Solubility in water	Insoluble
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Aluminium formate is the aluminium salt of formic acid, with the chemical formula Al(HCOO)₃. It can be produced via the reaction of aluminium soaps and formic acid.^[1] Reaction between formic acid and aluminium hydroxide yields Al(HCOO)₃(CO₂)_0.75(H₂O)_0.25(HCOOH)_0.25. Upon activation at 180 °C, guest molecules are removed to obtain Al(HCOO)₃.^[2]

References

^ Oskar, Jochem. "ALUMINIUM FORMATE AND PROCESS OF MAKING THE SAME". United States Patent Office. Retrieved 2012-06-29.^{[dead link]}
^ Evans H A, Mullangi D, Deng Z, et al. Aluminium formate, Al(HCOO)₃: An earth-abundant, scalable, and highly selective material for CO₂ capture. Science Advances, 2022, 8(44): eade1473. doi:10.1126/sciadv.ade1473

Hannelore, Rauh; Wilhelm Knoche (2010-06-10). "A kinetic study of the formation of aluminium formate in aqueous solution". Berichte der Bunsengesellschaft für physikalische Chemie. 83 (5): 518–521. doi:10.1002/bbpc.19790830513.
Xue, Moxi; Gao, Baoyu; Li, Ruihua; Sun, Jianzhang (2018). "Aluminium formate (AF): Synthesis, characterization and application in dye wastewater treatment". Journal of Environmental Sciences. 74: 95–106. doi:10.1016/j.jes.2018.02.013. PMID 30340679. S2CID 53010618.

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[1] Oskar, Jochem. "ALUMINIUM FORMATE AND PROCESS OF MAKING THE SAME". United States Patent Office. Retrieved 2012-06-29.^{[dead link]}

[2] Evans H A, Mullangi D, Deng Z, et al. Aluminium formate, Al(HCOO)₃: An earth-abundant, scalable, and highly selective material for CO₂ capture. Science Advances, 2022, 8(44): eade1473. doi:10.1126/sciadv.ade1473

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References

Further reading