Asymmetric catalytic oxidation
Asymmetric catalytic oxidation is a technique of oxidizing various substrates to give an enantiopure product using a catalyst.
Reactions
- Jacobsen epoxidation of alkenes using manganese-salen complex and NaOCl
- Sharpless epoxidation of allyl alcohols using titanium isopropoxide, diethyl tartrate, and tert-butyl hydroxyperoxide
- Sharpless asymmetric dihydroxylation of alkenes using dihydroquinine or dihydroquinidine ligands on an osmium metal center
- Sharpless oxyamination
- Shi epoxidation of alkenes using oxone and a fructose-derived chiral catalyst
- Sulfonyloxaziridine enolate oxidation
References
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