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Dicarbon monoxide

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Dicarbon monoxide
Names
IUPAC name
2-oxoethenylidene
Identifiers
3D model (JSmol)
  • [C]=C=O
Properties
Molar mass 40.02 g mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dicarbon monoxide (C2O) is an extremely reactive molecule that contains two carbon atoms and one oxygen atom. Dicarbon monoxide, covalently bonded, is a product of the photolysis of carbon suboxide.[1][2] It is closely related to CO, CO2 and C3O2, and other oxocarbons.

C3O2 → CO + C2O

It is stable enough to observe reactions with NO and NO2.[3]

References

  1. ^ Bayes K. (1961). "Photolysis of Carbon Suboxide". Journal of the American Chemical Society. 83: 3712–3713. doi:10.1021/ja01478a033.
  2. ^ Anderson D. J., Rosenfeld R. N. (1991). "Photodissociation of Carbon Suboxide". Journal of Chemical Physics. 94: 7852–7867. doi:10.1063/1.460121.
  3. ^ Thweatt W. D., Erickson M. A., Hershberger J. F. (2004). "Kinetics of the CCO+NO and CCO+NO2 reactions". Journal of Physical Chemistry. 108: 74–79. doi:10.1021/jp0304125.{{cite journal}}: CS1 maint: multiple names: authors list (link)