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Dimethylphosphite

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This is an old revision of this page, as edited by Graeme Bartlett (talk | contribs) at 02:01, 8 July 2017 (add identifiers from pubchem and chemspider; remove 868-85-9 as it is cas number for the ion). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Dimethylphosphite
Names
Other names
Phosphonic acid, dimethyl ester
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.011.622 Edit this at Wikidata
  • InChI=1S/C2H7O3P/c1-4-6(3)5-2/h3H,1-2H3
    Key: DLQDGVZAEYZNTG-UHFFFAOYSA-N
  • COP(O)OC
Properties
C2H7O3P
Molar mass 110.049 g·mol−1
Appearance colorless liquid
Density 1.20 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dimethylphosphite is an organophosphorus compound with the formula (CH3O)2P(O)H. It is a reagent for generating other organophosphorus compounds, exploiting the high reactivity of the P-H bond. The molecule is tetrahedral. It is a colorless liquid. The compounds can be prepared by methanolysis of phosphorus trichloride or by heating diethylphosphite in methanol.[1]

References

  1. ^ "Alcoholysis of Dialkyl Phosphites Under Microwave Conditions". Current Organic Chemistry. 17: 555–562. 2013. {{cite journal}}: Unknown parameter |authors= ignored (help)