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Mercury(II) sulfate

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Mercury(II) sulfate
Names
Other names
mercuric sulfate
Identifiers
ECHA InfoCard 100.029.083 Edit this at Wikidata
Properties
HgSO4
Molar mass 296.65 g/mol
Appearance white monoclinic crystals
Density 6.47 g/cm³, solid
reacts with water[1]
Solubility soluble in hot HSO4, NaCl solution
Thermochemistry
-707.5 kJ mol-1[2]
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability (red): no hazard codeInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Mercury(II) sulfate, commonly called mercuric sulfate is the chemical compound HgSO4. It is an odorless solid that forms white granules or crystalline powder. In water, it separates into an insoluble sulfate with a yellow color and sulfuric acid.

Mercury sulfate is used as a catalyst in the production of acetaldehyde from acetylene and water. Methyl mercury is produced as a side product of this conversion. Mercury-containing pollutants from this reaction are held to have caused Minamata disease in Minamata, Kumamoto prefecture, Japan.

References

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–70, ISBN 0849305942
  2. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 5–19, ISBN 0849305942