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Mercury(II) thiocyanate

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Mercury(II) thiocyanate
Names
Other names
mercuric thiocyanate
mercuric sulfocyanate
Identifiers
ECHA InfoCard 100.008.886 Edit this at Wikidata
Properties
Hg(SCN)2
Molar mass 316.79 g/mol
Appearance white monoclinic crystals
Density 3.71 g/cm³, solid
Melting point decomposes at 165°C
0.070 g/100 mL
Solubility soluble in dilute hydrochloric acid[1]
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability (red): no hazard codeInstability (yellow): no hazard codeSpecial hazards (white): no code
3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Mercury(II) thiocyanate (Hg(SCN)2) is a chemical compound. It was formerly used in pyrotechnics for the long snake-like ash Pharaoh's serpent that forms when a pellet of this compound, often with a small amount of a sugar such as glucose added to serve as supplemental fuel, is ignited. This is extremely dangerous because it produces poisonous mercury vapors.

Mercury(II) thiocyanate is made by reacting a mercury(II) salt (such as mercury(II) chloride) with a thiocyanate salt (such as potassium thiocyanate) in solution in water, producing a precipitate of mercury(II) thiocyanate.

References

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, FL: CRC Press, pp. 4–70, ISBN 0849305942