Metallum Martis, a 1665 book by Dud Dudley, is the earliest known reference to the use of coal in metallurgical smelting. The book is also referred to as Iron made with Pit-Coale, Sea-Coale, &c. And with the same Fuell to Melt and Fine Imperfect Mettals, And Refine perfect Mettals.
Many attendant difficulties had to be overcome before this fuel could be applied to the purpose of smelting iron. Dudley does not describe in his book how he was using coal, only that he was. In so doing, he described his use successively of an ironworks on Pensnett Chase and at Cradley, of a furnace at Himley, and of a furnace at Hasco Bridge near Gornal.
Dudley does mention several things that indicate what he was doing. The coal he used was the small pieces and slack which were "little or of no use in that inland country" and so brought in no money. This coal debris was left in heaps and "crowded moist slack heat naturally, and kindle in the middle of these great heaps, often sets the coal works on fire" and that "Also from these sulphurous heaps, mixed with ironstone (for out of many of the same pits is gotten much ironstone or mine), the fires heating vast quantities of water, passing through these soughs or adits becometh as hot as the bath at Bath". Dudley describes two rival attempts to smelt iron with coal instigated by supporters of Parliament during the Civil War and the Interregnum. Dudley visited both sites and having examined their furnaces and production methods, when asked his opinion, informed the proprietors that they would fail. The first attempt was by Captain Buck, with the backing of many parliamentary officers including Oliver Cromwell, with technical help from Edward Dagney, an Italian. In the second attempt in the late 1656–67 by Captain John Copley also failed despite Dudley, at no charge, improving the efficiency of Copley's bellows. Dudley reapplied for a patent from Charles II, in 1660 stating "and seeing no man able to perform the mastery of making of iron with pit-coal or sea-coal, ... [without my] laudable inventions the author was, and is, unwilling [that they] should fall to the ground and die with him".
Considered to be the earliest of recorded geologic maps, Metallum Martis marks a turning point in the evolution of scientific rationale concerning the recording and interpretation of geological information. It is considered to have been made at Castle Hill in Dudley by Dud Dudley in 1665.
- Dudley, Dudd (1854) , Bagnall, John N., ed., Dud Dudley's Metallum Martis: or, Iron made with pit-coale, sea-coale, &c: and with the same fuell to melt and fine imperfect mettals, and refine perfect mettals (reprint ed.), London
- King, P. W. (2002), "Dud Dudley's contribution to metallurgy", Historical Metallurgy, 36 (1): 43–53.
- Scrivenor, Harry (1854), A comprehensive history of the iron trade, London: Longman,Brown Green and Longmans, pp. 37–55 It includes an 18-page extract from, Metallum Martis.