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The Penex Process is a continuous catalytic process used in the refining of crude oil. It isomerizes light straight run naphtha (C5/C6) into higher-octane, branched C5/C6 molecules. It was first used commercially in 1958.
The Penex process uses fixed-bed catalysts containing chlorides. A single pass of feedstock with an octane rating of 50-60 through such a bed typically produces an end product rated at 82-86. If the feedstock is subsequently passed through a DIH (deisohexanizer) column, the end product typically has an octane rating of 87-90.5. If the feedstock is subsequently passed through a Molex-technology column, the end product typically has an octane rating of 88-91. If the feedstock is first passed through a DIP (deisopentanizer) column to remove iso-pentanes, then through the Penex bed, and subsequently through the DIH column, the end product typically has an octane rating of 91-93.
- http://www.uop.com/objects/TSPenexProcess.pdf UOP Penex Process website
- Takao, Kimura (2003). "Development of Pt/SO 4 2−/ZrO 2 catalyst for isomerization of light naphtha.". Catalysis Today. 81 (1): 57–63. doi:10.1016/s0920-5861(03)00102-0.
- Maples, Robert E. (2000). Petroleum refinery process economics. Penwell Books. p. 455. Retrieved 13 April 2015.
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