Syngenite

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Syngenite
Tapering crystal of syngenite (size: 4.4 x 1.3 x 0.6 cm)
General
CategorySulfate mineral
Formula
(repeating unit)
K2Ca(SO4)2·H2O
Strunz classification7.CD.35
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/m
Unit cella = 9.77 Å, b = 7.14 Å
c = 6.25 Å; β = 104.01°; Z = 2
Identification
ColorColorless, milky white to faintly yellow due to inclusions
Crystal habitTabular to prismatic crystals, lamellar aggregates and crystalline crusts
TwinningCommon on {101} contact twins
CleavagePerfect on {110} and {100}, distinct on {010}
FractureConchoidal
TenacityBrittle
Mohs scale hardness2.5
LusterVitreous
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.579–2.603
Optical propertiesBiaxial (-)
Refractive indexnα = 1.501 nβ = 1.517 nγ = 1.518
Birefringenceδ = 0.017
2V angleMeasured: 28°
References[1][2][3]

Syngenite is an uncommon potassium calcium sulfate mineral with formula K2Ca(SO4)2·H2O. It forms as prismatic monoclinic crystals and as encrustations.

Discovery and occurrence

It was first described in 1872 for an occurrence as druse on halite in the Kalusa Salt deposit, Ivanovo-Frankovsk Oblast', Ukraine.[2] The name is from Greek 'συγγενής' (related) due to its chemical similarity to polyhalite.[3][2]

It occurs in marine evaporite deposits as a diagenetic phase. It also forms as a volcanic sublimate, as vein fillings in geothermal fields and in caves where it is derived from bat guano. It occurs in association with halite and arcanite in salt deposits; and with biphosphammite, aphthitalite, monetite, whitlockite, uricite, brushite and gypsum in cave environments.[1]

References