Tetramethylphosphonium bromide

Tetramethylphosphonium bromide
Identifiers
CAS Number	4519-28-2;
3D model (JSmol)	Interactive image;
ChemSpider	317445;
ECHA InfoCard	100.152.249
PubChem CID	357594;
CompTox Dashboard (EPA)	DTXSID40326796 ;
	InChI InChI=1S/C4H12P.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1 Key: ZTXFOCMYRCGSMU-UHFFFAOYSA-M;
	SMILES C[P+](C)(C)C.[Br-];
Properties
Chemical formula	C4H12BrP
Molar mass	171.018 g·mol−1
Appearance	white solid
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H315, H319, H335
Precautionary statements	P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Tetramethylphosphonium bromide is an organophosphorus compound with the formula (CH₃)₄PBr. It is a white, water-soluble solid, the salt of the cation tetramethylphosphonium and the bromide anion. It is prepared by treating trimethylphosphine with methyl bromide. Deprotonation gives methylenetrimethylphosphorane.^[1]

References

^ H. F. Klein (1978). "Trimethylphosphonium Methylide (Trimethyl Methylenephosphorane)". Inorganic Syntheses. XVIII: 138–140. doi:10.1002/9780470132494.ch23.