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Trimethyloxonium tetrafluoroborate

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Trimethyloxonium tetrafluoroborate
Structural formula of trimethyloxonium tetrafluoroborate
Ball-and-stick models of the component ions of trimethyloxonium tetrafluoroborate
Names
IUPAC name
Trimethyloxonium tetrafluoroborate
Other names
Trimethyloxonium fluoborate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.006.360 Edit this at Wikidata
  • InChI=1S/C3H9O.BF4/c1-4(2)3;2-1(3,4)5/h1-3H3;/q+1;-1
    Key: CZVZBKHWOFJNCR-UHFFFAOYSA-N
  • F[B-](F)(F)F.[O+](C)(C)C
Properties
C3H9BF4O
Molar mass 147.91 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trimethyloxonium tetrafluoroborate Me3OBF4 (sometimes called the "Meerwein salt" after Hans Meerwein) is a strong methylating agent. It is the methyl analog to triethyloxonium tetrafluoroborate. Commercially available, this compound is prepared similarly, by reaction of boron trifluoride etherate with dimethyl ether and epichlorohydrin.[1]

References

  1. ^ T. J. Curphey (1988). "Trimethyloxonium Tetrafluoroborate". Organic Syntheses; Collected Volumes, vol. 6, p. 1019.