User:Benjah-bmm27/degree/2/DFW
Organometallics, DFW
[edit](eta-3-Cp)(CO)2-from-xtal-1978-3D-balls.png)
3(CO)2-anion-from-xtal-1982-3D-balls.png)
"Organo-Transition Metal Chemistry" http://www.ilpi.com/organomet/
- Organometallic chemistry
- d electron count, electron counting
- 18-Electron rule
- Metal carbonyls;
- Chromium hexacarbonyl, [Cr(CO)6]
- Dimanganese decacarbonyl, [Mn2(CO)10]
- Iron pentacarbonyl, [Fe(CO)5]
- Dicobalt octacarbonyl, [Co2(CO)8]
- Nickel tetracarbonyl, [Ni(CO)4]
- Homoleptic means all ligands the same
- Bridging ligands, e.g. CO in [(CpNi)3(CO)2]− – Jmol
- Fischer-Tropsch process
- Fluxionality
- Berry mechanism
- Mond process
- π backbonding: Dewar-Chatt-Duncanson model
- Phosphine
- Beta-hydride elimination
- Migratory insertion
- Hapticity (η notation)
- Carbenes, transition metal carbene complexes
- Zeise's salt
- 1,3-Butadiene as a ligand
