User:Graeme Bartlett/gallide
A gallide is an inorganic chemical compound containing anions composed of gallium atoms.
Gallium is outside the Zintl border, and so does not always form Zintl compounds with balanced electron numbers.[1] However for alkali metals compounds contain electron-precise icosahedral Ga12 or octahedral Ga6 clusters.
Some gallides form endohedral clusters, where a cluster of gallium atoms surrounds another metal atom.[1]
Formation
[edit]Gallides are formed by heating a metal with gallium, and then cooling slowly till crystallisation takes place. Liquid gallium is them remove by centrifuge.
List
[edit]| formula | space group | unit cell | volume | density | Superconductivity
Tc K |
comment | Reference | ||
|---|---|---|---|---|---|---|---|---|---|
| K3Ga13 | [1] | ||||||||
| V8Ga41 | P3 | a=13.9382 c=14.8924 | [1][2] | ||||||
| Mn6Ga29 | triclinic | P1 | a=6.3114 b=9.9557 c=18.920 α=90.473° β=90.847° γ=90.396 | monocapped distorted tetragonal antiprism (not MnGa6); phase transition at <145 | [3] | ||||
| Mn6Ga29 | monoclinic | a=6.2909 b = 9.9685 c = 31.431 β = 90.79°
the β pha |
145 to 210°C | ||||||
| Mn6Ga29 | tetragonal | P4/m | a = 6.3464 c = 10.0235 | >210°C melt incongruently at 390°C to MnGa4 | |||||
| MnGa4 | |||||||||
| CoGa3 | [1] | ||||||||
| Na10NiGa10 | [1] | ||||||||
| Y3Cu4Ga7 | [4] | ||||||||
| Mo8Ga41 | P3 | a=14.04 C=15.05 Z=1 | 856 | 6.95 | 9.8 | metallic | [1][5] | ||
| Mo6Ga31 | R3 | 8.0 | [1] | ||||||
| Rh2Ga9 | monoclinic | Pc | 2.0 | Ga9 single capped square antiprism | [1] | ||||
| Rh3Ga16 | orthorhombic | Ccca | a=30.424 b=6.4758 c=6.4677 | [6] | |||||
| Rh4Ga21 | orthorhombic | Cmca | a=40.135 b=6.4701 c=6.4727 | [6] | |||||
| PdGa | [7] | ||||||||
| Pd3Ga7 | [7] | ||||||||
| PdGa5 | tetragonal | I4/mcm | a=6.436 c=9.990 Z=4 | 1.6 | bicapped tetragonal antiprism | [8][9] | |||
| Ba5Ga6 | [1] | ||||||||
| LaGa6 | tetragonal | P4/nbm | a=6.094 c=7.692 | [10] | |||||
| NdGa6 | tetragonal | P4/nbm | a=5.996 c=7.62 | [10] | |||||
| SmGa6 | tetragonal | P4/nbm | a=5.963 c=7.608 | [10] | |||||
| Sm2Ru5Ga9 | tetragonal | I4/mmm | a=6.163 c=13.519 Z=2 | 513.5 | [11] | ||||
| Sm4Co3Ga16 | 2.8 | [1] | |||||||
| Sm2NiGa12 | [4] | ||||||||
| GdGa6 | tetragonal | P4/nbm | a=5.945 c=7.571 | [10] | |||||
| TbGa6 | tetragonal | P4/nbm | a=5.924 c=7.546 | [10] | |||||
| DyGa6 | tetragonal | P4/nbm | a=5.923 c=7.543 | [10] | |||||
| HoGa6 | tetragonal | P4/nbm | a=5.92 c=7.54 | [10] | |||||
| ErGa6 | tetragonal | P4/nbm | a=5.846 c=7.53 | [10] | |||||
| TmGa6 | tetragonal | P4/nbm | a=5.85 c 7.51 | [10] | |||||
| Yb2Ga | melt 655°C | [12] | |||||||
| YbGa | melt 895°C | [12] | |||||||
| TbGa2 | melt 1100°C | [12] | |||||||
| Yb3Ga8 | from 839 to 870° | [12] | |||||||
| YbGa4 | melt incongruently 755°C | [12] | |||||||
| YbGa5 | tetragonal | I4/mmm | a = 4.3059 c = 25.871 | Yb+2 | [13] | ||||
| YbGa6 | tetragonal | P4/nbm | a 5.849 c 7.601 | melt incongruently 282°C | [10] | ||||
| YbNiGa4 | orthorhombic | Cmcm | a = 4.0868 b = 15.2829 c = 6.5049 Z = 4 | [4][14] | |||||
| YbAgGa2 | [4] | ||||||||
| PtGa5 | P21/m | a = 6.3951 b = 15.882 c = 8.839 β = 110.26° | melt incongruently 294°C | [15] | |||||
| Pt3Ga7 | |||||||||
| Pt2Ta3Ga17 | hexagonal | P63/mmc | a = 8.1930 c = 13.6151 Z=2 | 8.884 | Pt@Ga6 trigonal prism; metallic | [16] | |||
| IrGa2 | orthorhombic | Cmcm | a=3.9021 b=12.9925 c=10.8808 | [17] | |||||
| Ir2Ga9 | monoclinic | Pc | 2.3 | Ga9 single capped square antiprism | [1] | ||||
| Ir3Ga5 | [17] | ||||||||
| IrGa3 | [17] | ||||||||
| Er2Os3Ga10 | tetragonal | P4/mbm | a= 8.834 c= 6.367 | 496.7 | 10.71 | metallic | [4] | ||
| Tm2Os3Ga10 | tetragonal | P4/mbm | a= 8.832 c= 6.336 | 494.3 | 10.79 | metallic | [4] | ||
| ReGa5 | orthorhombic | Cmce | a=9.2127 b=10.1043 c=9.2321 Z=8 | 859.40 | 2.3 | semiconductor; Re@Ga9 single-capped square antiprism | [1] | ||
| Re2Ga9Ge | tetragonal | P42/mmc | a = 8.0452 c = 6.7132 Z=2 | 436.643 | 8.157 | [18] | |||
| ReGa5Sn | tetragonal | P4/nmc | a=6.4680 c=10.166 Z=4 | 425.3 | [19] | ||||
| ReGa5Pb | tetragonal | P4/nmc | a=6.483 c=10.299 Z=4 | 429.9 | [19] | ||||
| ReGa5Bi | tetragonal | P4/nmc | a=6.474 10.213 Z=4 | 428.0 | [19] | ||||
| PuGa | tetragonal | I4mm | a = 6.641 c = 8.083 Z = 8 | [20] | |||||
| PuGa3 | [21] | ||||||||
| PuGa4 | orthorhombic | Imma | a=4.38 b=6.29 c=13.673 | 11.50 | [21] | ||||
| PuGa6 | tetragonal | P4/nbm | a=5.942 c=7.617 | [1][21] | |||||
| PuCoGa5 | 18.5 | [1] |
To do
[edit]follow up references from [4]
referenced in https://www.pnas.org/doi/full/10.1073/pnas.1522191112
follow reference to [14]
10.1021/ic801067g 10.1021/ic901059q 10.1002/ejic.201100289 10.1016/j.jssc.2010.06.011 10.1016/j.intermet.2013.04.008 10.1016/0025-5416(82)90075-1 10.1002/ejic.201100511 10.1007/bf02881277 10.1016/0022-5088(85)90133-X 10.1021/acs.chemmater.0c02311 10.1088/1361-648X/acc3ec 10.1143/jpsj.76.073708
https://scholar.google.com/scholar?start=20&hl=en&as_sdt=2005&sciodt=0,5&cites=6585612208659428456&scipsc= and onwards
https://scholar.google.com/scholar?cites=8497064484821542656&as_sdt=2005&sciodt=0,5&hl=en
https://scholar.google.com/scholar?cites=10955294918614096214&as_sdt=2005&sciodt=0,5&hl=en
References
[edit]- ^ a b c d e f g h i j k l m n o Xie, Weiwei; Luo, Huixia; Phelan, Brendan F.; Klimczuk, Tomasz; Cevallos, Francois Alexandre; Cava, Robert Joseph (2015-12-22). "Endohedral gallide cluster superconductors and superconductivity in ReGa 5". Proceedings of the National Academy of Sciences. 112 (51). doi:10.1073/pnas.1522191112. ISSN 0027-8424. PMC 4697388. PMID 26644566.
{{cite journal}}: CS1 maint: PMC format (link) - ^ Girgis, K.; Petter, W.; Pupp, G. (1975-01-01). "The crystal structure of V 8 Ga 41". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 31 (1): 113–116. doi:10.1107/S0567740875002191. ISSN 0567-7408.
- ^ Antonyshyn, Iryna; Prots, Yurii; Margiolaki, Irene; Schmidt, Marcus Peter; Zhak, Olga; Oryshchyn, Stepan; Grin, Yuri (2013-03). "Tetragonal-antiprismatic coordination of transition metals in intermetallic compounds: ω1-Mn6Ga29 and its structuralrelationships". Journal of Solid State Chemistry. 199: 141–148. doi:10.1016/j.jssc.2012.12.002.
{{cite journal}}: Check date values in:|date=(help) - ^ a b c d e f g Jeitschko, Wolfgang; Schlüter, Martin (2009-05-01). "The Lanthanoid Osmium Gallides Er 2 Os 3 Ga 10 and Tm 2 Os 3 Ga 10 with Yb 2 Ru 3 Ga 10 -type Structure". Zeitschrift für Naturforschung B. 64 (5): 499–503. doi:10.1515/znb-2009-0504. ISSN 1865-7117.
- ^ Yvon, K. (1975-01-01). "Mo 8 Ga 41 , another example of ten-coordination of the transition element". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 31 (1): 117–120. doi:10.1107/S0567740875002208. ISSN 0567-7408.
- ^ a b Boström, Magnus; Prots, Yurii; Grin, Yuri (2006-08). "Preparation, crystal structure and chemical bonding analysis of the new binary compounds Rh4Ga21 and Rh3Ga16". Journal of Solid State Chemistry. 179 (8): 2472–2478. doi:10.1016/j.jssc.2006.04.045.
{{cite journal}}: Check date values in:|date=(help) - ^ a b Kovnir, K.; Osswald, J.; Armbrüster, M.; Giedigkeit, R.; Ressler, T.; Grin, Yu.; Schlögl, R. (2006), "PdGa and Pd3Ga7: Highly-Selective Catalysts for the Acetylene Partial Hydrogenation", Studies in Surface Science and Catalysis, vol. 162, Elsevier, pp. 481–488, doi:10.1016/s0167-2991(06)80943-2, ISBN 978-0-444-52827-8, retrieved 2024-03-14
- ^ Grin, Yuri; Wedig, Ulrich; Wagner, Frank; von Schnering, Hans Georg; Savin, Andreas (1997-06). "The analysis of "empty space" in the PdGa5 structure". Journal of Alloys and Compounds. 255 (1–2): 203–208. doi:10.1016/S0925-8388(96)02836-8.
{{cite journal}}: Check date values in:|date=(help) - ^ Ryżyńska, Zuzanna; Wiśniewski, Piotr; Kaczorowski, Dariusz; Xie, Weiwei; Cava, Robert J.; Klimczuk, Tomasz; Winiarski, Michal̷ J. (2021-05-27). "Superconductivity in the Endohedral Ga Cluster Compound PdGa 5". The Journal of Physical Chemistry C. 125 (20): 11294–11299. doi:10.1021/acs.jpcc.1c03615. ISSN 1932-7447.
- ^ a b c d e f g h i j Pelleg, Joshua; Kimmel, G.; Dayan, D. (1981-09). "RGa6 (R≡ rare earth atom), a common intermetallic compound of the R-Ga systems". Journal of the Less Common Metals. 81 (1): 33–44. doi:10.1016/0022-5088(81)90266-6.
{{cite journal}}: Check date values in:|date=(help) - ^ Schlüter, M.; Jeitschko, W. (2002-12). "Crystal structure of the gallium-rich intermetallic compound Sm2Ru5Ga9 with a new superstructure of the CsCl-type". Zeitschrift für Kristallographie - New Crystal Structures. 217 (JG): 27–28. doi:10.1524/ncrs.2002.217.jg.27. ISSN 2197-4578.
{{cite journal}}: Check date values in:|date=(help) - ^ a b c d e Giedigkeit, Rainer (2007). Strukturelle Ordnung und Unordnung in bin¨aren und tern¨aren Verbindungen des Galliums mit Ytterbium und Palladium. Dresden.
{{cite book}}: line feed character in|title=at position 35 (help) - ^ Giedigkeit, Rainer; Niewa, Rainer; Schnelle, Walter; Grin, Yuri; Kniep, Rüdiger (2002-07). "On the Binary Compound YbGa5Dedicated to Professor Welf Bronger on the Occasion of his 70th Birthday". Zeitschrift für anorganische und allgemeine Chemie. 628 (7): 1692. doi:10.1002/1521-3749(200207)628:7<1692::AID-ZAAC1692>3.0.CO;2-Y.
{{cite journal}}: Check date values in:|date=(help) - ^ a b Vasylechko, L.; Schnelle, W.; Schmidt, M.; Burkhardt, U.; Borrmann, H.; Schwarz, U.; Grin, Yu. (2006-06). "Valence behaviour of ytterbium in YbNiGa4". Journal of Alloys and Compounds. 416 (1–2): 35–42. doi:10.1016/j.jallcom.2005.08.060.
{{cite journal}}: Check date values in:|date=(help) - ^ Iryna Antonyshyn, Magnus Boström, Stefan Hoffmann, Marcus Schmidt, Franz Weitzer , Yurii Prots, and Yuri Grin. "Low-Temperature Chemistry in the Binary Systems of Pt and Mn with Gallium" (PDF). pp. 152–154.
{{cite web}}: CS1 maint: multiple names: authors list (link) - ^ Tillard, Monique (2021-09). "Flux growth synthesis, single crystal and electronic structure of the new intermetallic compound Pt2Ga17Ta3". Computational Materials Science. 197: 110591. doi:10.1016/j.commatsci.2021.110591.
{{cite journal}}: Check date values in:|date=(help) - ^ a b c Boström, Magnus; Prots, Yurii; Grin, Yuri (2004-05). "Synthesis, crystal structure and chemical bonding of the novel compound IrGa2". Solid State Sciences. 6 (5): 499–503. doi:10.1016/j.solidstatesciences.2004.02.009.
{{cite journal}}: Check date values in:|date=(help) - ^ Likhanov, Maxim S.; Verchenko, Valeriy Yu.; Zhupanov, Vladislav O.; Wei, Zheng; Dikarev, Evgeny V.; Kuznetsov, Alexey N.; Shevelkov, Andrei V. (2022-01-10). "Intermetallic Compound Re 2 Ga 9 Ge with Re- and Ge-Embedded Gallium Clusters: Synthesis, Crystal Structure, Chemical Bonding, and Physical Properties". Inorganic Chemistry. 61 (1): 568–578. doi:10.1021/acs.inorgchem.1c03240. ISSN 0020-1669.
- ^ a b c Marshall, Madalynn; Górnicka, Karolina; Mudiyanselage, Ranuri S. Dissanayaka; Klimczuk, Tomasz; Xie, Weiwei (2019-10-14). "New Tetragonal ReGa5(M) (M = Sn, Pb, Bi) Single Crystals Grown from Delicate Electrons Changing". Crystals. 9 (10): 527. doi:10.3390/cryst9100527. ISSN 2073-4352.
{{cite journal}}: CS1 maint: unflagged free DOI (link) - ^ Roof, R. B. (1979-12-01). "Crystal data for room temperature PuGa". Journal of Applied Crystallography. 12 (6): 619–621. doi:10.1107/S0021889879013479. ISSN 0021-8898.
- ^ a b c Ellinger, F. H.; Zachariasen, W. H. (1965-08-01). "The crystal structures of PuGa 4 and PuGa 6". Acta Crystallographica. 19 (2): 281–283. doi:10.1107/S0365110X65003250. ISSN 0365-110X.