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User:Graeme Bartlett/tellurostannate

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Tellurostannates are chemical compounds containing anions with tellurium bound to tin. There are also tellurogermanates, thiostannates and selenidostannates.

Related compounds may substitute tellurium with selenium and sulfur to produce a range of hetero-chalcogenidostannates.[1]


10.1016/j.poly.2022.115729


List

[edit]
name chem mw crystal system space group unit cell Å volume density comment CAS

no

references
Li4[SnIV2Te6]·8en [2]
[enH]4[SnIV2Te6]·en triclinic P1 a 11.755 b 11.978 c 13.985, α 77.12° β 74.74° γ 62.98° [2]
[Na4(en)4][SnTe4] P21/c a=7.599 b=26.496 c=13.710 β: 92.84° 2756.8 [3]
[K4(H2O)0.5][SnTe4] monoclinic C2/c a 21.523 b 11.518 c 15.708 β 130.53° [4]
[K4(H2O)(en)][SnTe4] triclinic P1 a 8.486 b 8.712 c 13.500 α 93.47° β 104.14° γ 90.83° [4]
Tetraphenylphosphonium (μ3-telluro)-(μ2-methanol)-(μ2-telluro)-dimethanol-telluro-potassium-tin PPh4[K(MeOH)3(OH)][SnTe5] triclinic P1 a 11.0590 b 12.7370 c 13.3224 α 75.252° β 67.782° γ 76.021° [5]
[Mn(en)3]2[Sn2Te6] orthorhombic Pbca a=15.797 b=12.640 c=20.175 Z=4 4028.4 [6]
tris(Ethylene-1,2-diamine)-manganese (μ2-tellurido)-ditelluro-tin dihydrate [Mn(en)3][SnTe4]·2H2O triclinic P1 a=9.311 b=9.435 c=12.800 α 108.36° β 98.43° γ 103.82° 1005.8 [3]
teta = triethylenetetramine and en = ethylenediamine [Mn(teta)(en)]·[Mn(teta)][Mn(SnTe4)2·Mn(teta)] 1972.74 tetragonal a=14.4726 c =24.0551 Z=4 5032.8 2.604 band gap 0.88 eV [7]
(NMe4)2[MnSnTe4] monoclinic C2/m a=17.440 b=7.035 c=9.465 β=117.90 Z=2 1026.3 2.694 black [8]
K10[Mn4(μ4-Te)(SnTe4)4]·20H2O cubic I43m a=16.0889 Z=2 4164.7 2.883 black [9]
[Zn(en)3]2[Sn2Te6] monoclinic P21/n a=9.048 b = 22.300 c = 9.360 β=103.19 Z = 4 [10]
bis(μ2-Tellurido)-bis(triethylenetetra-amine)-ditellurido-tin-di-zinc {Zn(teta)}2(μ-1κ:2κ-SnTe4) monoclinic P21 a=8.4254 b=11.3038 c=15.2973 β=100.063° [11]
tris(μ2-Tellurido)-tris(triethylenetetra-amine)-tellurido-tin-tri-zinc bis(iodide) [{Zn(teta)}3(μ3-1κ:2κ:3κ-SnTe4)]I2 orthorhombic P212121 a=11.536 b=15.266 c=24.076 [11]
tetrakis(μ2-Tellurido)-bis(tris(2-aminoethyl)amine)-ditellurido-di-tin-di-zinc {Zn(tren)}2(μ-1κ:2κ-Sn2Te6) monoclinic P21/c a=8.360 b 13.002 c=14.809 β=95.41° [11]
bis(bis(diethylenetriamine)-zinc) bis(μ-tellurido)-tetratellurido-di-tin ethylenediamine [Zn(dien)2]4(Sn2Te6)1.75(Sn2Te8)0.25·dien monoclinic P21/c a=17.146 b=15.132 c=17.158 β=97.65° [11]
K10[Zn4(μ4-Te)(SnTe4)4]·20H2O cubic I43m a=15.965 Z=2 4069.3 2.984 black [9]
[Rb4(H2O)2][SnTe4] monoclinic C2/c a =19.993 b =7.8225 c =14.22 β =129.33° [4]
[Rb4(H2O)0.67(en)0.33][SnTe4] P3 a=22.812 c=11.871 [4]
K10[Cd4(μ4-Te)(SnTe4)4]·20H2O cubic I43m a=16.142 Z=2 4206.3 3.036 black [9]
Rb10[Cd4(μ4-Te)(SnTe4)4]·20H2O cubic I43m a=16.100 Z=2 4173.4 3.429 black [9]
[Cs4(H2O)2][SnTe4] monoclinic C2/c a 20.757 b 8.0418 c 14.624 β 129.31° [4]
[Cs4(H2O)0.5(en)0.5][SnTe4] P3 a=23.632 c 12.227 [4]
Cs2[MnSnTe4] [8]
[Rb2Ba(H2O)11][SnTe4] monoclinic P21 a=8.5232 b=15.095 c=9.5538 β=97.03° [4]
K10[Hg4(μ4-Te)(SnTe4)4]·20H2O cubic I43m a=16.076 Z=2 4154.6 3.355 black [9]
(en = ethylenediamine) [Mn(en)3]HgSnTe3(Te2) 1192.53 tetragonal P42/bc a=16.828 c=16.659 [12]
(dien = diethylenetriamine) [Mn(dien)2]HgSnTe3(Te2) monoclinic P21/n a=11.542 b=13.400 c=15.630 β=95.20° [12]
[Fe(dien)2]HgSnTe3(Te2) monoclinic P21/n a=11.501 b=13.481 c=15.503 β=93.80° [12]
Rb2[HgSnTe4] tetragonal I42m a=8.776 c=7.353 Z=2 565.0 5.882 black [8]
Cs6 3∞{[Hg4(μ4-Te)(SnTe4)3]6−} trigonal R3m a=15.880 c=17.367 Z=3 3793.0 4.842 black [9]

References

[edit]
  1. ^ Ruzin, Eugen; Zent, Eldar; Matern, Eberhard; Massa, Werner; Dehnen, Stefanie (18 May 2009). "Syntheses, Structures, and Comprehensive NMR Spectroscopic Investigations of Hetero-Chalcogenidometallates: The Right Mix toward Multinary Complexes". Chemistry - A European Journal. 15 (21): 5230–5244. doi:10.1002/chem.200802060. PMID 19360821.
  2. ^ a b Dehnen, Stefanie; Zimmermann, Christian (2002). "Syntheses, Crystal Structures, and Reactivity of [enH]4[Sn2Se6]·en, [enH]4[Sn2Te6]·en and [enH]4[Sn2S6]: Known Anions within Novel Coordination Spheres obtained by Novel Synthesis Routes". Zeitschrift für Anorganische und Allgemeine Chemie. 628 (11): 2463–2469. doi:10.1002/1521-3749(200211)628:11<2463::AID-ZAAC2463>3.0.CO;2-Y.
  3. ^ a b Ruzin, Eugen; Zimmermann, Christian; Hillebrecht, Pierre; Dehnen, Stefanie (May 2007). "Syntheses and Structures of Solvated Tetrasodiumtetrachalcogenostannates [Na4(en)4][SnE4] (en = 1,2-diaminoethane; E = Te, Se), and their Reactions Toward Further Ternary or Quaternary Chalcogenometallates [Mn(en)3]2[Sn2Te6]·4H2O or [Na10(H2O)34][Mn4(μ4-Se)(SnSe4)4]". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (5–6): 820–829. doi:10.1002/zaac.200700071.
  4. ^ a b c d e f g Ruzin, Eugen; Kracke, Andreas; Dehnen, Stefanie (May 2006). "Efficient Synthesis and Properties of Single-Crystalline [SnTe4]4− Salts". Zeitschrift für anorganische und allgemeine Chemie (in German). 632 (6): 1018–1026. doi:10.1002/zaac.200600051. ISSN 0044-2313.
  5. ^ Ruzin, Eugen; Massa, Werner; Dehnen, Stefanie (October 2007). "Treating [K 4 (H 2 O) 0.5 ][SnTe 4 ] with PPh 4 + or AsPh 4 + : Formation of a Highly Air-Stable Tellurostannate Salt, a Tellurolate with One-Coordinate Te Atoms, and a Polytelluride Salt with ∞ 1 [Te 4 (H 2 O) 2 ] 2– Chains". European Journal of Inorganic Chemistry. 2007 (28): 4429–4433. doi:10.1002/ejic.200700726. ISSN 1434-1948.
  6. ^ Chen, Yao; Liu, Xing; Zhou, Jian; Zou, Hua-hong; Xiang, Bin (2021-02-15). "One-Dimensional Vanadium(III) Chalcogenidostannates Incorporating [V(tepa)] 3+ Complexes as Bridging Groups". Inorganic Chemistry. 60 (4): 2127–2132. doi:10.1021/acs.inorgchem.0c03484. ISSN 0020-1669. PMID 33503370. S2CID 231765552.
  7. ^ Zhang, Qichun; Bu, Xianhui; Lin, Zhien; Biasini, Maurizio; Beyermann, W. P.; Feng, Pingyun (2007-09-01). "Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix". Inorganic Chemistry. 46 (18): 7262–7264. doi:10.1021/ic701135h. ISSN 0020-1669. PMID 17665909.
  8. ^ a b c Thiele, Günther; Peter, Sabrina; Schwarzer, Martin; Ruzin, Eugen; Clérac, Rodolphe; Staesche, Halgard; Rößer, Carola; Roling, Bernhard; Dehnen, Stefanie (2012-03-19). "Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity". Inorganic Chemistry. 51 (6): 3349–3351. doi:10.1021/ic300075a. ISSN 0020-1669. PMID 22384785.
  9. ^ a b c d e f Ruzin, Eugen; Fuchs, Andreas; Dehnen, Stefanie (2006). "Fine-tuning of optical properties with salts of discrete or polymeric, heterobimetallic telluride anions [M 4 (μ 4 -Te)(SnTe 4 ) 4 ] 10− (M = Mn, Zn, Cd, Hg) and 3∞{[Hg 4 (μ 4 -Te)(SnTe 4 ) 3 ] 6− }". Chem. Commun. (46): 4796–4798. doi:10.1039/B610833D. ISSN 1359-7345. PMID 17345732.
  10. ^ Li, Jing; Chen, Zhen; Emge, Thomas J.; Yuen, Tan; Proserpio, Davide M. (May 1998). "Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)32(Sn2Te6) (M = Mn, Zn)". Inorganica Chimica Acta. 273 (1–2): 310–315. doi:10.1016/S0020-1693(97)06035-0.
  11. ^ a b c d Lu, Jialin; Wang, Fang; Shen, Yali; Tang, Chunying; Zhang, Yong; Jia, Dingxian (August 2014). "New μ-SnTe4 and μ-Sn2Te6 ligands to transition metal: Solvothermal syntheses and characterizations of zinc tellurostannates containing polyamine ligands". Journal of Solid State Chemistry. 216: 65–72. Bibcode:2014JSSCh.216...65L. doi:10.1016/j.jssc.2014.05.002.
  12. ^ a b c Yang, Xiao; Ren, Taohong; Zhu, Hongjin; Jia, Dingxian (2024-04-15). "Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury–Tellurostannate Hybrids with Transition-Metal Complexes". Inorganic Chemistry. 63 (15): 6638–6648. doi:10.1021/acs.inorgchem.3c04400. ISSN 0020-1669. PMID 38556744.
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