User:Oldstar79/Plasmonic Solar Cells

Plasmonic Solar Cells (PSC) are known as photovoltaic devices. They have great potential in driving the cost of solar power down. In order for the solar cell (SC) technology to be a viable energy source to compete with fossil fuels, the price needs to be reduced 2-5x. Approximately 90% of the market for solar cells use silicon wafers. These wafers are typically around 200-300μm and constitute about 40% of the cost. PSCs are a type of thin-film SC which are typically 1-2μm thick. They also use substrates which are cheaper than silicon, such as, glass, plastic or steel. The biggest problem for thin film SCs is that they don’t absorb as much light as the current SCs. Methods for trapping light on the surface, or in the SC are crucial in order to make thin film SCs viable.

Current SCs have ways of trapping light. However, their method is to create pyramids on the surface which have dimensions bigger than most thin film SCs. Making the surface of the substrate rough (typically by growing SnO₂ or ZnO on surface) with dimensions on the order of the incoming wavelengths and depositing the SC on top has been explored. This method increases the photocurrent, but the thin film SC would then have poor material quality.

Other methods have been explored for increasing the absorption of light in thin film SCs. One method which has been explored over the past few years is to scatter light using metal nanoparticles excited at their surface Plasmon resonance. Different approaches using these metal nanoparticles and the basic principles which govern how the scattering/absorption is increased will be the focus of the following information.

History

People

There have been quite a few pioneers working with plasmonic solar cells. One of the main focuses has been on improving the thin film SC through the use of metal nanoparticles distributed on the surface. It has been found that the Raman scattering can be increased by order of magnitude when using metal nanoparticles. The increased Raman scattering provides more photons to become available to excite surface plasmons which cause electrons to be excited and travel through the thin film SC to create a current. The list below shows a few of research which has been done to improve PSCs.

• Stuart and Hall: Photocurrent enhancement by 18x with 165nm SOI photodetector with wavelength of 800nm using silver nanoparticles used for scattering and absorption of light.

• Schaadt: Gold nanoparticles used for scattering and absorption of light on doped silicon obtaining 80% enhancements with 500nm wavelength.

• Derkacs: Gold nanoparticles on thin-film silicon gaining 8% on conversion efficiency.

• Pillai: Silver particles on SOI obtaining 33% photocurrent increase.

• Stenzel: Enhancements in photocurrent by a factor of 2.7 for ITO-copper phthalocyanine-indium structures.

• Westphalen: Enhancement for silver clusters incorporated into ITO and zinc phthalocyanine solar cells.

• Rand: Enhanced efficiencies for ultra thin film organic solar cells due to 5nm diameter silver nanoparticles.

Devices

There are currently three different generations of SCs. The first generation (those in the market today) are made with crystalline semiconductor wafers, typically silicon. These are the SCs everybody thinks of when they hear "Solar Cell". The second generation SCs are based on thin film technologies such as those presented here. These SCs focus on lowering the amount of material used as well as increasing the energy production. Third generation SCs are currently being researched. They focus on reducing the cost of the second generation SCs. The third generation SCs are discussed in more detail under recent advancement.

Design

The design for a PSC varies depending on the method being used to trap and scatter light across the surface and through the material.

Metal Nanoparticle Plasmonic Solar Cell

PSC using metal nanoparticles.

A common design is to deposit metal nanoparticles on the top surface of the thin film SC. When light hits these metal nanoparticles at their surface plasmon resonance, the light is scattered in many different directions. This allows light to travel along the SC and bounce between the substrate and the nanoparticles enabling the SC to absorb more light.

Metal Film Plasmonic Solar Cell

A plasmonic solar cell utilizing metal film to distribute light and enhance absorption.

PSC using metal film.

Other methods utilizing surface plasmons for harvesting solar energy are available. One other type of structure is to have a thin film of silicon and a thin layer of metal deposited on the lower surface. The light will travel through the silicon and generate surface plasmons on the interface of the silicon and metal. This generates electric fields inside of the silicon since electric fields do not travel very far into metals. If the electric field is strong enough, electrons can be moved and collected to produce a photocurrent. The thin film of metal in this design must have nanometer sized grooves which act as waveguides for the incoming light in order to excite as many photons in the silicon thin film as possible.

Basic Principles

General

Thin film SC (left) and Typical SC (right).

When a photon is excited in the substrate of a SC, an electron and hole are separated. Once the electrons and holes are separated, they will want to recombine since they are of opposite charge. If the electrons can be collected prior to this happening then the SC is pretty efficient. The way to collect the electrons quickly would be to make the conducting material very thin. If the surface is made very thin, there will be less light absorbed by the device. A thick device absorbs more light.

Metal Nanoparticles

Scattering and Absorption

The basic principles for the functioning of plasmonic solar cells include scattering and absorption of light due to the deposition of metal nanoparticles. Silicon does not absorb light very well. For this reason, more light needs to be scattered across the surface in order to increase the absorption. It has been found that metal nanoparticles help to scatter the incoming light across the surface of the silicon substrate. The equations that govern the scattering and absorption of light can be shown as:

• $C_{scat}={\frac {1}{6\pi }}\left({\frac {2\pi }{\lambda }}\right)^{4}|\alpha |^{2}$

This shows the scattering of light for particles which have diameters below the wavelength of light.

• $C_{abs}={\frac {2\pi }{\lambda }}Im[\alpha ]$

This shows the absorption for a point dipole model.

• $\alpha =3V\left[{\frac {\epsilon _{p}/\epsilon _{m}-1}{\epsilon _{p}/\epsilon _{m}+2}}\right]$

This is the polarizability of the particle. V is the particle volume. $\epsilon _{p}$ is the dielectric function of the particle. $\epsilon _{m}$ is the dielectric function of the embedding medium. When $\epsilon _{p}=-2\epsilon _{m}$ the polarizability of the particle becomes large. This polarizability value is know as the surface plasmon resonance. The dielectric function for metals with low absorption can be defined as:

• $\epsilon =1-{\frac {\omega _{p}}{\omega ^{2}+i\gamma \omega }}$

In the previous equation, $\omega _{p}$ is the bulk plasmon frequency. This is defined as:

• $\omega _{p}^{2}=Ne^{2}/m\epsilon _{0}$

N is the density of free electrons, e is the electronic charge and m is the effective mass of an electron. $\epsilon _{0}$ is the dielectric constant of free space. The equation for the surface plasmon resonance in free space can therefore be represented by:

• $\alpha =3V{\frac {\omega _{p}^{2}}{\omega _{p}^{2}-3\omega ^{2}-i\gamma \omega }}$

Many of the plasmonic solar cells use nanoparticles to enhance the scattering of light. These nanoparticles take the shape of spheres, and therefore the surface plasmon resonance frequency for spheres is desirable. By solving the previous equations, the surface plasmon resonance frequency for a sphere in free space can be shown as:

• $\omega _{sp}={\sqrt {3}}\omega _{p}$

As an example, at the surface plasmon resonance for a silver nanoparticle, the scattering cross-section is about 10x the cross-section of the nanoparticle. The goal of the nanoparticles is to trap light on the surface of the SC. The absorption of light is not important for the nanoparticle, rather, it is important for the SC. One would think that if the nanoparticle is increased in size, then the scattering cross-section becomes larger. This is true, however, when compared with the size of the nanoparticle, the ratio (${\frac {CS_{scat}}{CS_{particle}}}$) is reduced. Particles with a large scattering cross section tend to have a broader plasmon resonance range.

Wavelength Dependence

Surface plasmon resonance mainly depends on the density of free electrons in the particle. The order of densities of electrons for different metals is shown below along with the type of light which corresponds to the resonance.

• Aluminum - Ultra-violet
• Silver - Ultra-violet
• Gold - Visible
• Copper - Visible

If the dielectric constant for the embedding medium is varied, the resonant frequency can be shifted. Higher indexes of refraction will lead to a longer wavelength frequency.

Light Trapping

The metal nanoparticles are deposited at a distance from the substrate in order to trap the light between the substrate and the particles. The particles are embedded in a material on top of the substrate. The material is typically a dielectric, such as silicon or silicon nitride. When performing experiment and simulations on the amount of light scattered into the substrate due to the distance between the particle and substrate, air is used as the embedding material as a reference. It has been found that the amount of light radiated into the substrate decreases with distance from the substrate. This means that nanoparticles on the surface are desirable for radiating light into the substrate, but if there is no distance between the particle and substrate, then the light is not trapped and more light escapes.

Metal Film

As light is incident upon the surface of the metal film, it excites surface plasmons. The surface plasmon frequency is specific for the material, but through the use of gratings on the surface of the film, different frequencies can be obtained. The surface plasmons are also preserved through the use of waveguides as they make the surface plasmons easier to travel on the surface and the losses due to resistance and radiation are minimized. The electric field generated by the surface plasmons influences the electrons to travel toward the collecting substrate.

Materials

First Generation	Second Generation	Third Generation
Single-crystal silicon	CuInSe2	Gallium Indium Phosphide
Multicrystalline silicon	amorphous silicon	Gallium Indium Arsenide
Polycrystalline silicon	thin film crystalline Si	Germanium

Applications

The applications for plasmonic solar cells are endless. The need for cheaper and more efficient solar cells is huge. In order for solar cells to be considered cost effective, they need to provide energy for a smaller price than that of traditional power sources such as coal and gasoline. The movement toward a more green world has helped to spark research in the area of plasmonic solar cells. Currently, solar cells cannot exceed efficiencies of about 30% (First Generation). With new technologies (Third Generation), efficiencies of up to 40-60% can be expected. With a reduction of materials through the use of thin film technology (Second Generation), prices can be driven lower.

Space

Certain applications for plasmonic solar cells would be for space exploration vehicles. A main contribution for this would be the reduced weight of the solar cells. An external fuel source would also not be needed if enough power could be generated from the solar cells. This would drastically help to reduce the weight as well.

Rural

Solar cells have a great potential to help rural electrification. An estimated two million villages near the equator have limited access to electricity and fossil fuels and that approximately 80% of people in the world do not have access to electricity. When the cost of extending power grids, running rural electricity and using diesel generators is compared with the cost of solar cells, many times the solar cells win. If the efficiency and cost of the current solar cell technology is decreased even further then many rural communities and villages around the world could obtain electricity when current methods are out of the question. Specific applications for rural communities would be water pumping systems, residential electric supply and street lights. A particularly interesting application would be for health systems in countries where motorized vehicles are not overly abundant. Solar cells could be used to provide the power to refrigerate medications in coolers during transport.

Solar cells could also provide power to lighthouses, buoys, or even oil rigs out in the ocean. Industrial companies could use them to power telecommunications systems or monitoring and control systems along pipelines or other system.

High Power

If the solar cells could be produced on a large scale and be cost effective then entire power stations could be built in order to provide power to the electrical grids. With a reduction in size, they could be implemented on both commercial and residential buildings with a much smaller footprint. They might not even seem like an eyesore.

Other areas are in hybrid systems. The solar cells could help to power high consumption devices such as automobiles in order to reduce the amount of fossil fuels used and to help improve the environmental conditions of the earth.

Low Power

One application which has not been mentioned is consumer electronics. Essentially, solar cells could be used to replace batteries for low power electronics. This would save everyone a lot of money and it would also help to reduce the amount of waste going into landfills.

Recent Advancements

Light Trapping

As discussed earlier, being able to concentrate and scatter light across the surface of the plasmonic solar cell will help to increase efficiencies. Recently, research at Sandia National Labs has discovered a photonic waveguide which collects light at a certain wavelength and traps it within the structure. This new structure can contain 95% of the light that enters it compared to 30% for other traditional waveguides. It can also direct the light within one wavelength which is ten times greater than traditional waveguides. The wavelength this device captures can be selected by changing the structure of the lattice which comprises the structure. If this structure is used to trap light and keep it in the structure until the solar cell can absorb it, the efficiency of the solar cell could be increased dramatically.

Absorption

Another recent advancement in plasmonic solar cells is using other methods to aid in the absorption of light. One way being researched is the use of metal wires on top of the substrate to scatter the light. This would help by utilizing a larger area of the surface of the solar cell for light scattering and absorption. The danger in using lines instead of dots would be creating a reflective layer which would reject light from the system. This is very undesirable for solar cells. This would be very similar to the thin metal film approach, but it also utilizes the scattering effect of the nanoparticles.

Third Generation Solar Cells

The goal of third generation solar cells is to increase the efficiency using second generation solar cells (thin film) and using materials that are found abundantly on earth. This has also been a goal of the thin film solar cells. With the use of common and safe materials, third generation solar cells should be able to be manufactured in mass quantities further reducing the costs. The initial costs would be high in order to produce the manufacturing processes, but after that they should be cheap. The way third generation solar cells will be able to improve efficiency is to absorb a wider range of frequencies. The current thin film technology has been limited to one frequency due to the use of single band gap devices.

Multiple Energy Levels

The idea for multiple energy level solar cells is to basically stack thin film solar cells on top of each other. Each thin film solar cell would have a different band gap which means that if part of the solar spectrum was not absorbed by the first cell then the one just below would be able to absorb part of the spectrum. These can be stacked and an optimal band gap can be used for each cell in order to produce the maximum amount of power. Options for how each cell is connected are available, such as serial or parallel. The serial connection is desired because the output of the solar cell would just be two leads.

The lattice structure in each of the thin film cells needs to be the same. If it is not then there will be losses. The processes used for depositing the layers are complex. They include Molecular Beam Epitaxy and Metal Organic Vapour Phase Epitaxy. The current efficiency record is made with this process but doesn't have exact matching lattice constants. The losses due to this are not as effective because the differences in lattices allows for more optimal band gap material for the first two cells. This type of cell is expected to be able to be 50% efficient.

Lower quality materials that use cheaper deposition processes are being researched as well. These devices are not as efficient, but the price, size and power combined allow them to be just as cost effective. Since the processes are simpler and the materials are more readily available, the mass production of these devices is more economical.