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Ytterbium(III) acetylacetonate

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Ytterbium(III) acetylacetonate
Names
Other names
ytterbium(III) acetylacetonate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/3C5H8O2.Yb/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3
    Key: CVEKUGFVEWLJFN-UHFFFAOYSA-K
  • CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Yb+3]
Properties
C15H21O6Yb
Molar mass 470.372 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ytterbium(III) acetylacetonate is a coordination compound with the chemical formula Yb(C5H7O2)3(H2O)2. Its structure is different from the acetylacetone complexes of neodymium, europium and holmium. The adjacent Yb-Yb The distance is 8.3 Å.[1] Yb(acac)3(bpy) can be obtained by reacting its trihydrate with 2,2'-bipyridine in ethanol.[2]

References

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  1. ^ Korytnyl, E. F.; Aslanov, L. A.; Poral-Koshits, M. A.; Petrukhin, O. M. (1968). "Structure of ytterbium tris-acetylacetonate". Journal of Structural Chemistry (in Russian). 9 (3): 466. doi:10.1007/bf00738845. ISSN 0022-4766. S2CID 96776164.
  2. ^ Korytnyi, E. F.; Dzyubenko, N. G.; Aslanov, L. A.; Martynenko, L. I. (1981-04-21). "Tris(acetylacetonato)ytterbium adduct with 2,2'-bipyridine". Chemischer Informationsdienst. 12 (16). doi:10.1002/chin.198116075. ISSN 0009-2975.