Anthracene-9-carbaldehyde
Appearance
(Redirected from 9-Anthracenecarboxaldehyde)
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Names | |
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Preferred IUPAC name
Anthracene-9-carbaldehyde | |
Other names
9-Anthraldehyde, 9-Anthracenaldehyde, Anthracene-9-carbaldehyde
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Identifiers | |
3D model (JSmol)
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639167 | |
ChemSpider | |
ECHA InfoCard | 100.010.349 |
EC Number |
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PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
C15H10O | |
Molar mass | 206.244 g·mol−1 |
Appearance | yellow solid |
Melting point | 104 °C (219 °F; 377 K) |
Hazards | |
GHS labelling: | |
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Warning | |
H302, H312, H315, H319, H332, H335 | |
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Anthracene-9-carbaldehyde is the most common monoaldehyde derivative of anthracene. It is a yellow solid that is soluble in common organic solvents. It is prepared by Vilsmeier formylation of anthracene.[1][2] The compound is also used as a building block for supramolecular assemblies.[3] Hydrogenation of 9-anthracenecarboxaldehyde gives 9-anthracenemethanol.
References
[edit]- ^ Fieser, L. F.; Hartwell, J. L.; Jones, J. E.; Wood, J. H.; Bost, R. W. (1940). "9-Anthraldehyde; 2-Ethoxy-1-Naphthaldehyde". Organic Syntheses. 20: 11. doi:10.15227/orgsyn.020.0011.
- ^ Jones, Gurnos; Stanforth, Stephen P. (1996). "The Vilsmeier Reaction of Fully Conjugated Carbocycles and Heterocycles". Organic Reactions. pp. 1–330. doi:10.1002/0471264180.or049.01. ISBN 0471264180.
- ^ Lindsey, Jonathan S.; Wagner, Richard W. (1989). "Investigation of the Synthesis of ortho-Substituted Tetraphenylporphyrins". The Journal of Organic Chemistry. 54 (4): 828–836. doi:10.1021/jo00265a021.