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Urbach tail

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Bulk absorption coefficient α calculated with the band-gap model (blue dotted line), the Urbach-tail extension (red dotted line), and the band-gap model with Urbach tail (black solid line).
Band-gap model (blue dotted line), the Urbach-tail extension (red dotted line), and the band-gap model with Urbach tail (black solid line).

Urbach Tail is an exponential part in the absorbtion coefficient curve. This tail appears near the optical band edge, in the amorphous, disordered and crystaline materials.

Urbach Empirical Rule

History

Researchers were questioning the nature of the disordered semiconductors' tale states since the nineteen-fifties. It has been found that such tails arise from the strains sufficient to push local states past the band edges. In 1953 F.Urbach identified that such tails decay exponentially into the gap[1]. Later photoemission experiments delivered absorbtion models displaying temperature dependence of the tail[2]. Variety amorphous and imperfect crystalline solids reveal exponential band edges via optical absorption. The surprising universality of this feature suggested the possibility of a common cause. Several attempts to explain the phenomenon were limited, and could not connect specific topological units to the electronic structure[3][4]

Recent studies showed that topological filaments (structural patterns that resemble hydrodynamic flow fields) can be a structure underlying the Urbach edge. However, TF might be not unique in producing the Urbach tail[5]

References

  1. ^ Urbach, Franz (1953-12-01). "The Long-Wavelength Edge of Photographic Sensitivity and of the Electronic Absorption of Solids". Physical Review. 92 (5): 1324. Bibcode:1953PhRv...92.1324U. doi:10.1103/physrev.92.1324. ISSN 0031-899X.
  2. ^ Aljishi, Samer; Cohen, J. David; Jin, Shu; Ley, Lothar (1990-06-04). "Band tails in hydrogenated amorphous silicon and silicon-germanium alloys". Physical Review Letters. 64 (23): 2811–2814. Bibcode:1990PhRvL..64.2811A. doi:10.1103/physrevlett.64.2811. ISSN 0031-9007. PMID 10041817.
  3. ^ Bacalis, N.; Economou, E. N.; Cohen, M. H. (1988-02-15). "Simple derivation of exponential tails in the density of states". Physical Review B. 37 (5): 2714–2717. Bibcode:1988PhRvB..37.2714B. doi:10.1103/physrevb.37.2714. ISSN 0163-1829. PMID 9944833.
  4. ^ Cohen, M. H.; Chou, M.-Y.; Economou, E. N.; John, S.; Soukoulis, C. M. (January 1988). "Band tails, path integrals, instantons, polarons, and all that". IBM Journal of Research and Development. 32 (1): 82–92. doi:10.1147/rd.321.0082. ISSN 0018-8646.
  5. ^ Pan, Y.; Inam, F.; Zhang, M.; Drabold, D. A. (2008-05-21). "Atomistic Origin of Urbach Tails in Amorphous Silicon". Physical Review Letters. 100 (20): 206403. arXiv:0802.1292. Bibcode:2008PhRvL.100t6403P. doi:10.1103/physrevlett.100.206403. ISSN 0031-9007. PMID 18518560. S2CID 18393428.