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Xenon trioxide

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Xenon trioxide
Xenon trioxide
General
Systematic name xenon trioxide
xenon(VI) oxide
Molecular formula XeO3
Molar mass 179.288 g/mol
Appearance colorless crystalline solid
CAS number [13776-58-4]
Properties
Density and phase 4.55 g/cm3, solid
Solubility in water Soluble (with reaction)
Melting point 25 °C Violent Decomposition
Acidity (pKa) ?
Structure
Molecular shape trigonal pyramidal
Bond length ? pm (Xe−O)
Dipole moment ?
Thermodynamic data
Standard enthalpy
of formation
ΔfH°solid
402 kJ/mol
Standard molar entropy
S°solid
? J.K−1.mol−1
Hazards
EU classification not listed
NFPA 704
NFPA 704
safety square
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 4: Readily capable of detonation or explosive decomposition at normal temperatures and pressures. E.g. nitroglycerinSpecial hazards (white): no code
4
3
4
Supplementary data page
Structure and
properties
n, εr, etc.
Thermodynamic
data
Phase behaviour
Solid, liquid, gas
Spectral data UV, IR, NMR, MS
Related compounds
Related compounds Perxenic acid
Xenon tetroxide
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references

Xenon trioxide is an unstable compound of xenon in its +6 oxidation state. It is a very powerful oxidizing agent, and liberates oxygen (and xenon) from water slowly, accelerated by exposure to sunlight. It is dangerously explosive upon contact with organic materials.

When it dissolves in water, an acidic solution of xenic acid is formed:

XeO3(aq) + H2O → H2XeO4 → H+ + HXeO4

References

  1. Webelements periodic table: page on Xenon(VI) oxide

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