Diethylenetriamine
Identifiers | |
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3D model (JSmol)
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605314 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.003.515 |
EC Number |
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2392 | |
MeSH | diethylenetriamine |
PubChem CID
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RTECS number |
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
C4H13N3 | |
Molar mass | 103.169 g·mol−1 |
Appearance | Colourless liquid |
Odor | Ichtyal, ammoniacal |
Density | 955 mg mL−1 |
Melting point | −39.00 °C; −38.20 °F; 234.15 K |
Boiling point | 204.1 °C; 399.3 °F; 477.2 K |
log P | −1.73 |
Vapor pressure | 10 Pa (at 20 °C) |
Refractive index (nD)
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1.484 |
Thermochemistry | |
Heat capacity (C)
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254 J K−1 mol−1 (at 40 °C) |
Std enthalpy of
formation (ΔfH⦵298) |
−65.7–−64.7 kJ mol−1 |
Std enthalpy of
combustion (ΔcH⦵298) |
−3367.2–−3366.2 kJ mol−1 |
Hazards | |
GHS labelling: | |
Danger | |
H302, H312, H314, H317 | |
P280, P305+P351+P338, P310 | |
Flash point | 102 °C |
Explosive limits | 2–6.7% |
Related compounds | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Diethylenetriamine (abbreviated DETA) is an organic compound with the formula HN(CH2CH2NH2)2. This colourless hygroscopic liquid is soluble in water and polar organic solvents, but not simple hydrocarbons. Diethylenetriamine is structural analogue of diethylene glycol. Its chemical properties resemble those for ethylene diamine, and it has similar uses. It is a weak base and its aqueous solution is alkaline. DETA is a byproduct of the production of ethylenediamine from ethylene dichloride.[1]
Reactions and uses
In coordination chemistry, it serves as a tridentate ligand forming complexes such as Co(dien)(NO2)3.[2]
Like some related amines, it is used in oil industry for the extraction of acid gas.
Like ethylenediamine, DETA can also be used to sensitize nitromethane, making a liquid explosive compound similar to PLX. This compound is cap sensitive with an explosive velocity of around 6200 m/s and is discussed in patent #3,713,915. Mixed with unsymmetrical dimethylhydrazine it was used as Hydyne, a propellent for liquid-fuel rockets.
See also
References
- ^ Eller, K.; Henkes, E.; Rossbacher, R.; Höke, H. "Amines, Aliphatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a02_001. ISBN 978-3527306732.
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: CS1 maint: multiple names: authors list (link) - ^ Crayton, P. H.; Zitomer, F.; Lambert, J. (1963). "Inner Complexes of Cobalt(III) with Diethylenetriamine". In Kleinberg, J. (ed.). Inorganic Syntheses. Vol. 7. pp. 207–213. doi:10.1002/9780470132388.ch56.
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: CS1 maint: multiple names: authors list (link)