Bismuthine: Difference between revisions
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{{short description|Chemical compound of bismuth and hydrogen}} |
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| ImageName1 = Skeletal formula of bismuthine |
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| ImageSize2 = 110px |
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| ImageName2 = Spacefill model of bismuthine |
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| ImageCaption2 = {{legend|9e4fb5|Bismuth, Bi}}{{legend|white|Hydrogen, H}} |
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| SystematicName = |
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| CASNo_Ref = {{cascite|correct|??}} |
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| UNII_Ref = {{fdacite|correct|FDA}} |
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| UNII = OCH2V0Z37N |
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| PubChem = 9242 |
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| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} |
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| ChemSpiderID = 8886 |
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| InChI = 1/Bi.3H/rBiH3/h1H3 |
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| InChIKey = BPBOBPIKWGUSQG-PVKOQVOWAF |
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| StdInChI_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChI = 1S/Bi.3H |
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| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} |
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| StdInChIKey = BPBOBPIKWGUSQG-UHFFFAOYSA-N |
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| Section2 = {{Chembox Properties |
| Section2 = {{Chembox Properties |
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| Formula = BiH<sub>3</sub> |
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| MolarMass = 212.00 g/mol |
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| Appearance = colourless gas |
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| Density = 0.008665 g/mL (20 °C) |
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| MeltingPt = |
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| BoilingPtC = 16.8 |
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| BoilingPt_notes = (extrapolated) |
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| Solubility = |
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| ConjugateAcid = Bismuthonium |
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| Section3 = {{Chembox Structure |
| Section3 = {{Chembox Structure |
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| MolShape = trigonal pyramidal |
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| Autoignition = |
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| FlashPt = |
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| Section9 = {{Chembox Related |
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| OtherFunction = [[Ammonia]]<br>[[Phosphine]]<br>[[Arsine]]<br>[[Stibine]] |
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| OtherFunction_label = [[hydrides]] |
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'''Bismuthine''' (IUPAC name: '''bismuthane''') is the [[chemical compound]] with the formula |
'''Bismuthine''' (IUPAC name: '''bismuthane''') is the [[chemical compound]] with the formula [[Bismuth|Bi]][[Hydrogen|H]]<sub>3</sub>. As the heaviest analogue of [[ammonia]] (a [[pnictogen hydride]]), BiH<sub>3</sub> is unstable, decomposing to [[bismuth]] metal well below 0 °C. This compound adopts the expected pyramidal structure with H–Bi–H angles of around 90°.<ref name="Jerzembeck">{{ cite journal | journal = Angew. Chem. Int. Ed.| year = 2002 | volume = 41 | issue = 14 | pages = 2550–2552 | title = Bismuthine BiH<sub>3</sub>: Fact or Fiction? High-Resolution Infrared, Millimeter-Wave, and Ab Initio Studies |author1=W. Jerzembeck |author2=H. Bürger |author3=L. Constantin |author4=L. Margulès |author5=J. Demaison |author6=J. Breidung |author7=W. Thiel | url = http://www3.interscience.wiley.com/journal/96516335/abstract | archive-url = https://archive.today/20130105102945/http://www3.interscience.wiley.com/journal/96516335/abstract | url-status = dead | archive-date = 2013-01-05 | doi = 10.1002/1521-3773(20020715)41:14<2550::AID-ANIE2550>3.0.CO;2-B | pmid = 12203530 | url-access = subscription }}</ref> |
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The term ''bismuthine'' may also refer to a member of the family of organobismuth(III) species having the general formula {{chem|BiR|3}}, where R is an organic substituent. For example, Bi(CH<sub>3</sub>)<sub>3</sub> is ''trimethylbismuthine''. |
The term ''bismuthine'' may also refer to a member of the family of organobismuth(III) species having the general formula {{chem|BiR|3}}, where R is an organic substituent. For example, Bi(CH<sub>3</sub>)<sub>3</sub> is ''trimethylbismuthine''. |
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==Preparation and properties== |
==Preparation and properties== |
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BiH<sub>3</sub> is prepared by the redistribution of methylbismuthine (BiH<sub>2</sub>Me):<ref name=Holl>Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001.ISBN |
BiH<sub>3</sub> is prepared by the redistribution of methylbismuthine (BiH<sub>2</sub>Me):<ref name=Holl>Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001.{{ISBN|0-12-352651-5}}.</ref> |
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:3 BiH<sub>2</sub>Me → 2 BiH<sub>3</sub> + BiMe<sub>3</sub> |
:3 BiH<sub>2</sub>Me → 2 BiH<sub>3</sub> + BiMe<sub>3</sub> |
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The required BiH<sub>2</sub>Me, which is also thermally unstable, is generated by reduction of methylbismuth dichloride, BiCl<sub>2</sub>Me with [[Lithium aluminium hydride|LiAlH<sub>4</sub>]].<ref name="Jerzembeck" /> |
The required BiH<sub>2</sub>Me, which is also thermally unstable, is generated by reduction of [[methylbismuth dichloride]], BiCl<sub>2</sub>Me with [[Lithium aluminium hydride|LiAlH<sub>4</sub>]].<ref name="Jerzembeck" /> |
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As suggested by the behavior of [[stibine|SbH<sub>3</sub>]], BiH<sub>3</sub> is unstable |
As suggested by the behavior of [[stibine|SbH<sub>3</sub>]], BiH<sub>3</sub> is unstable and decomposes to its constituent elements according to the following equation: |
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:2 BiH<sub>3</sub> → 3 H<sub>2</sub> + 2 Bi |
:2 BiH<sub>3</sub> → 3 H<sub>2</sub> + 2 Bi {{pad|4em}}(Δ''H''{{su|b=f|p=<s>o</s>}}(gas) = −278 kJ/mol) |
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The methodology used for detection of arsenic ("[[Marsh test]]") can also be used to detect BiH<sub>3</sub>. This test relies on the thermal decomposition of these trihydrides to the metallic mirrors of |
The methodology used for detection of [[arsenic]] ("[[Marsh test]]") can also be used to detect BiH<sub>3</sub>. This test relies on the [[thermal decomposition]] of these trihydrides to the metallic mirrors of reduced As, Sb, and Bi. These deposits can be further distinguished by their distinctive solubility characteristics: arsenic dissolves in [[sodium hypochlorite|NaOCl]], antimony dissolves in [[polysulfide|ammonium polysulfide]], and bismuth resists both reagents.<ref name=Holl/> |
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==Uses and safety considerations== |
==Uses and safety considerations== |
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The low stability of BiH<sub>3</sub> |
The low stability of BiH<sub>3</sub> precludes significant health effects, it decomposes rapidly well below room temperature. |
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==References== |
==References== |
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{{Bismuth compounds}} |
{{Bismuth compounds}} |
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{{Hydrides by group}} |
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==External links== |
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[[Category:Bismuth compounds]] |
[[Category:Bismuth compounds]] |
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[[Category:Metal hydrides]] |
[[Category:Metal hydrides]] |
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[[de:Bismutan]] |
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[[nl:Bismutine]] |
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[[ja:ビスムチン]] |
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[[pl:Bizmutowodór]] |
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[[ru:Висмутин (газ)]] |
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[[simple:Bismuthine]] |
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[[zh:䏟]] |