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Chlorodimethylsilane: Difference between revisions

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{{Orphan|date=February 2009}}
{{chembox
{{chembox
| Verifiedfields = changed
| verifiedrevid = 396310739
| verifiedrevid = 412835735
| Reference = <ref> [[Sigma-Aldrich]] ''Handbook of Fine Chemicals'' 2007, page 654.</ref>
| Reference = <ref> [[Sigma-Aldrich]] ''Handbook of Fine Chemicals'' 2007, page 654.</ref>
| ImageFileL1 = Chlorodimethylsilane.png
| ImageFileL1 = Chlorodimethylsilane formula V.1.svg
| ImageSizeL1 = 120px
| ImageFileR1 = Chlorodimethylsilane_(structure).png
| ImageFileR1 = Chlorodimethylsilane_(structure).png
| PIN = Chlorodi(methyl)silane
| ImageSizeR1 = 140px
| IUPACName = Chlorodimethylsilane
| OtherNames = Dimethylchlorosilane, DMCS
| OtherNames = Dimethylchlorosilane, DMCS
| Section1 = {{Chembox Identifiers
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 59496
| ChemSpiderID = 59496
| InChI = 1/C2H7ClSi/c1-4(2)3/h4H,1-2H3
| InChI = 1/C2H7ClSi/c1-4(2)3/h4H,1-2H3
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| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 1066-35-9
| CASNo = 1066-35-9
| UNII_Ref = {{fdacite|changed|FDA}}
| PubChem =
| SMILES = Cl[SiH](C)C
| UNII = XR7E4F5838
| PubChem = 6327132
| EC_number = 213-912-0
| UNNumber = 2924
| SMILES = Cl[SiH](C)C
}}
}}
| Section2 = {{Chembox Properties
|Section2={{Chembox Properties
| Formula = (CH<sub>3</sub>)<sub>2</sub>SiHCl
| Formula = (CH<sub>3</sub>)<sub>2</sub>SiHCl
| MolarMass = 94.62 g/mol
| MolarMass = 94.62 g/mol
| Appearance =
| Appearance =
| Density = 0.852 g/mL, 25 °C
| Density = 0.852 g/mL, 25 °C
| MeltingPt = -111 °C
| MeltingPtC = -111
| BoilingPt = 34.7 °C
| BoilingPtC = 34.7
| Solubility =
| Solubility =
}}
}}
| Section3 = {{Chembox Hazards
|Section3={{Chembox Hazards
| MainHazards =
| MainHazards =
| FlashPt =
| FlashPt =
| Autoignition =
| AutoignitionPt =
| GHSPictograms = {{GHS02}}{{GHS05}}{{GHS06}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|224|261|314|331}}
| PPhrases = {{P-phrases|210|231+232|233|240|241|242|243|260|261|264|271|280|301+330+331|303+361+353|304+340|305+351+338|310|311|321|363|370+378|402+404|403+233|403+235|405|501}}
}}
}}
| Section8 = {{Chembox Related
|Section8={{Chembox Related
| Function =
| OtherFunction_label =
| OtherAnions =
| OtherAnions =
| OtherCations =
| OtherCations =
| OtherCpds = [[Dichloromethylsilane]], [[Trichlorosilane]], [[Trimethylsilane]]
| OtherCompounds = [[Dichloromethylsilane]], [[Trichlorosilane]], [[Trimethylsilane]]
| OtherFunctn = }}
| OtherFunction = }}
}}
}}


'''Chlorodimethylsilane''', also called '''dimethylchlorosilane''' and abbreviated '''DMCS''', is a [[chemical compound]] with the formula (CH<sub>3</sub>)<sub>2</sub>SiHCl. It is a [[silane]], with a [[silicon]] atom bonded to two [[methyl]] groups, a [[chlorine]] atom, and a [[hydrogen]] atom.
'''Chlorodimethylsilane''', also called '''dimethylchlorosilane''' and abbreviated '''DMCS''', is a [[chemical compound]] with the formula (CH<sub>3</sub>)<sub>2</sub>SiHCl. It is a [[silane]], with a [[silicon]] atom bonded to two [[methyl]] groups, a [[chlorine]] atom, and a [[hydrogen]] atom.


Its structure, including [[bond length]]s and [[bond angle]]s, has been determined using [[Fourier transform]] [[microwave spectroscopy]].<ref>{{cite journal |last=Kawashima |first=Y. |authorlink= |coauthors= |year=2001 |month=May |title=The rotational spectrum of chlorodimethylsilane using Fourier transform microwave spectroscopy |journal=[[Journal of Molecular Structure]] |volume=563-564 |issue= |pages=227–230 |id= |url=http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TGS-435M5SD-13&_user=10&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000050221&_version=1&_urlVersion=0&_userid=10&md5=ee6bbf3a55e66bb4aa52f0925657b86c |accessdate=2008-02-08 |quote= |doi=10.1016/S0022-2860(00)00879-6 }}</ref>
Its structure, including [[bond length]]s and [[bond angle]]s, has been determined using [[Fourier transform]] [[microwave spectroscopy]].<ref>{{cite journal |last=Kawashima |first=Y. |date=May 2001 |title=The rotational spectrum of chlorodimethylsilane using Fourier transform microwave spectroscopy |journal=[[Journal of Molecular Structure]] |volume=563-564 |issue=1–3 |pages=227–230 |doi=10.1016/S0022-2860(00)00879-6 |bibcode=2001JMoSt.563..227K }}</ref>


==References==
==References==
{{reflist}}
{{reflist}}


[[Category:Silanes]]
[[Category:Chlorosilanes]]


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