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Canada balsam

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Canada balsam, also called Canada turpentine or balsam of fir, is a turpentine made from the resin of the balsam fir tree (Abies balsamea) of boreal North America. The resin, dissolved in essential oils, is a viscous, sticky, colourless or yellowish liquid that turns to a transparent yellowish mass when the essential oils have been allowed to evaporate.

Canada balsam is amorphous when dried. Since it does not crystallize with age, its optical properties do not deteriorate.[citation needed] However, it has poor thermal and solvent resistance.[1]

Uses

Slide of 60-year-old holotype specimen of a flatworm (Lethacotyle fijiensis) permanently mounted in Canada balsam

Due to its high optical quality and the similarity of its refractive index to that of crown glass (n = 1.55), purified and filtered Canada balsam was traditionally used in optics as an invisible-when-dry glue for glass, such as lens elements. Lenses glued with Canada balsam (or with other similar glues) are called cemented lenses. Also, other optical elements can be cemented with Canada balsam, such as two prisms bonded to form a beam splitter. Balsam was phased out as an optical adhesive during World War II, in favour of polyester, epoxy, and urethane-based adhesives. In modern optical manufacturing, UV-cured epoxies are often used to bond lens elements.

Canada balsam was also commonly used for making permanent microscope slides. From about 1830 molten Canada balsam was used for microscope slides, then Canada balsam in solution was introduced in 1843, becoming popular in the 1850s.[2] In biology, for example, it can be used to conserve microscopic samples by sandwiching the sample between a microscope slide and a glass coverslip, using Canada balsam to glue the arrangement together and enclose the sample to conserve it. Xylene balsam, Canada balsam dissolved in xylene, is also used for preparing slide mounts.[3] Some workers prefer terpene resin for slide mounts, as it is both less acidic and cheaper than balsam. Synthetic resins have largely replaced organic balsams for such applications.

Another important application of Canada balsam is in the construction of the Nicol prism. A Nicol prism consists of a calcite crystal cut into two halves. Canada balsam is placed between the two layers. Calcite is an anisotropic crystal and has different refractive indices for rays polarized along directions parallel and perpendicular to its optic axis. These rays with differing refractive indices are known as the ordinary and extraordinary rays. The refractive index for Canada balsam is in between the refractive index for the ordinary and extraordinary rays. Hence the ordinary ray will be totally internally reflected. The emergent ray will be linearly polarized, and traditionally this has been one of the popular ways of producing polarized light.

Some other uses (traditional and current) include:

  • in geology, it is used as a common thin section cement and glue and for refractive-index studies and tests, such as the Becke line test;
  • to fix scratches in glass (car glass, for instance) as invisibly as possible;
  • in oil painting, to achieve glow and facilitate fusion;
  • in Buckley's cough syrup.

See also

References

  1. ^ "The Bonding of Optical Elements – Techniques and Troubleshooting". Summers Optical. Archived from the original on February 20, 2007. Retrieved 10 Feb 2009. {{cite journal}}: Cite journal requires |journal= (help); Unknown parameter |deadurl= ignored (|url-status= suggested) (help)
  2. ^ Bracegirdle, Brian (1989-09-01). "The development of biological preparative techniques for light microscopy, 1839–1989". Journal of Microscopy. 155 (3): 307–318. doi:10.1111/j.1365-2818.1989.tb02892.x. ISSN 1365-2818.
  3. ^ Gage, Simon Henry (1941). The Microscope (17 ed.). Ithaca, NY: Comstock. p. 443. OCLC 547782.