John F. Hartwig

John F. Hartwig
File:Prof. John F. Hartwig at his 2014 Nagoya Award Lecture.jpg Hartwig delivering his 2014 award lecture for the 2014 Nagoya Medal of Organic Chemistry
Born	John F. Hartwig 1964 (Elmhurst, IL) United States
Nationality	American
Alma mater	Ph.D (1990) University of California, Berkeley A.B. (1986) Princeton University
Known for	Organometallic chemistry, inorganic chemistry, Catalysis
Awards	Willard Gibbs Award (2015)
Scientific career
Fields	Chemistry
Institutions	University of California, Berkeley
Doctoral advisors	Robert G. Bergman and Richard A. Anderson

John F. Hartwig is the Henry Rapoport Professor of Chemistry at the University of California, Berkeley. His laboratory studies focus on developing new methods for the preparation of a broad range of organic compounds. His explorations have illustrated the potential of the transition metal-catalyzed construction of important carbon-carbon and carbon-heteroatom linkages in a way that has elevated such transformations to strategy level reactions.

Hartwig is known for helping develop the Buchwald–Hartwig amination, a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides. Here is an example of this reaction:

The Buchwald–Hartwig reaction

He also helped develop a technique for steric-directed C–H borylation of arenes. The versatility of this method is described in the following reaction scheme:

Meta-functionalization of arenes through C–H borylation

Hartwig received his A.B. from Princeton University in 1986, and earned his Ph.D. in Chemistry from the University of California, Berkeley in 1990.

Career

• 1984: General Electric Research and Development, Schenectady, NY
• 1985: Monsanto Japan Ltd., Kawachi, Japan
• 1986-1989: University of California, Berkeley, Berkeley, CA Graduate Student Instructor.
• 1990 - 1992: Massachusetts Institute of Technology, Cambridge, MA American Cancer Society Postdoctoral Associate.
• 1992-1996: Yale University, New Haven, CT Assistant Professor of Chemistry.
• 1996-1998: Yale University, New Haven, CT Associate Professor of Chemistry.
• 1998-2004: Yale University, New Haven, CT Professor of Chemistry.
• 2004-2006: Yale University, New Haven, CT Irénée duPont Professor of Chemistry
• 2006-2011: University of Illinois at Urbana–Champaign, Kenneth L. Reinhart Jr. Professor of Chemistry.
• 2011-present: Lawrence Berkeley National Laboratory, Berkeley Senior Faculty Scientist
• 2011-present: University of California, Berkeley Henry Rapoport Professor of Chemistry.

Academy Memberships and Fellowships

• 2015: Member, American Academy of Arts and Sciences
• 2012: Member, National Academy of Sciences
• 2005: Fellow of the American Association for the Advancement of Science

Major Awards

2015	Willard Gibbs Award
2013	Herbert C. Brown Award for Creative Research in Synthetic Methods
2010	GlaxoSmithKline Scholars Award
2009	National Institutes of Health MERIT Award
2009	Edward Mack Jr. Memorial Award, Ohio State University
2009	Mitsui Chemicals Catalysis Science Award, Japan
2009	Joseph Chatt Award of the Royal Society of Chemistry
2008	International Catalysis Award from the International Association of Catalysis Society
2008	Mukaiyama Award from the Society of Synthetic Organic Chemistry, Japan
2008	de of the Organic Reactions Catalysis Society
2007	Raymond and Beverly Sackler Prize in the Physical Sciences
2007	Tetrahedron Young Investigator Award in Organic Synthesis
2006	ACS Award in Organometallic Chemistry
2004	Thieme-IUPAC Prize in Synthetic Organic Chemistry
2003	Leo Hendrik Baekeland Award
1998	A. C. Cope Scholar Award
1997	Camille Dreyfus Teacher-Scholar Award
1992	Dreyfus Foundation New Faculty Award

Publications

• Hartwig, John (2010). Organotransition Metal Chemistry: From Bonding to Catalysis. New York: University Science Books. p. 1160. ISBN 978-1-938787-15-7.