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m-Anisidine

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m-Anisidine
Skeletal formula of m-anisidine
Ball-and-stick model of the m-anisidine molecule
Names
Preferred IUPAC name
3-Methoxyaniline
Other names
m-Anisidine (no longer recommended[1])
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.867 Edit this at Wikidata
EC Number
  • 208-651-4
UN number 2431
  • InChI=1S/C7H9NO/c1-9-7-4-2-3-6(8)5-7/h2-5H,8H2,1H3 checkY
    Key: NCBZRJODKRCREW-UHFFFAOYSA-N checkY
  • InChI=1/C7H9NO/c1-9-7-4-2-3-6(8)5-7/h2-5H,8H2,1H3
  • Nc1cccc(OC)c1
Properties[2]
C7H9NO
Molar mass 123.15 g/mol
Appearance pale yellow oily liquid
Density 1.096 (20 °C), liquid
Melting point < 0 °C (32 °F; 273 K)
Boiling point 251 °C (484 °F; 524 K)
Solubility soluble in ethanol, diethyl ether, acetone, benzene
1.5794
Hazards
Flash point > 122 °C (252 °F; 395 K)
515 °C (959 °F; 788 K)
Related compounds
Related compounds
o-Anisidine
p-Anisidine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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m-Anisidine one of the three isomers of anisidine. It is very poisonous for the blood leading to pink coloration of the skin and inner suffocation. Additionally its vapors are irritating to eyes, mucous membranes, the respiratory system and skin.

References

  1. ^ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 669. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4. The names 'toluidine', 'anisidine', and 'phenetidine' for which o-, m-, and p- have been used to distinguish isomers, and 'xylidine' for which numerical locants, such as 2,3-, have been used, are no longer recommended, nor are the corresponding prefixes 'toluidine', 'anisidino', 'phenetidine', and 'xylidino'.
  2. ^ Weast, Robert C., ed. (1981). CRC Handbook of Chemistry and Physics (62nd ed.). Boca Raton, FL: CRC Press. p. C-98. ISBN 0-8493-0462-8..