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Nelsonite

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Nelsonite
Igneous rock
A speckled rock with black (ilmenite) and white (apatite) grains
Nelsonite from Nelson County, Virginia
Composition
Ilmenite and apatite
Identification[1]
Formula FeO.TiO2.nFe2O3

Ca3(F,Cl)(PO4)3

Hardness 5 - 6
Specific gravity 3.7 - 4.1 bulk; ilmenite: 4.5-5.0
Streak ilmenite: black to brownish-red

apatite: white

Color black metallic and light-colored
Habit even-granular texture
Luster metallic to sub-metallic
Fracture conchoidal
Tenacity brittle
Texture holocrystalline

Nelsonite is an igneous rock primarily constituted of ilmenite and apatite, with anatase, chlorite, phosphosiderite, talc and/or wavellite appearing as minor components. Rocks are equigranular with a grain size around 2 – 3 mm.[2] The black ilmenite is slightly magnetic while the whitish apatite is not.[3]

Name

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It was named for Nelson County, Virginia, and is also found in that state's Amherst and Roanoke counties. In 2016, the Virginia legislature designated it as the official State Rock of Virginia.[4]

Use

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At one time, it was mined for the primary extraction of titanium dioxide. Titanium dioxide from ilmenite is used as a white paint pigments[5] and in the early 1900's as a colorant of artificial teeth.[1][6] The calcium phosphate from apatite is used as agricultural fertilizer.[6] While no active mining of Nelsonite occurs in Virginia, active mining occurs in parts of China for rare-earth elements.[3][6][2]

Formation

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Anorthosite-related nelsonite occurs mainly as veins and lensoidal intrusions in anorthosite complex or wall rocks.[7] The Fe–Ti–P-rich magma liquids formed immiscible and eutectic mixtures crystallizing around 850-1,000 °C followed by intense fractionation.[8][6] Disagreement exists on the role liquid immiscibility plays in generating nelsonite and Fe–Ti oxides ore.[7] It is not common to have such relatively large density differentials of mineral constituents as seen in Nelsonite; ilmenite (4.7–5.2 g/cm3) and apatite (~ 3.5 g/cm3).[7] Nelsonites experience differential weathering. Exposed apatite within the Nelsonite is readily removed through solution by meteoric waters that can result in a cellular or sponge-like ilmenite mass.[1]

Occurrence

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Nelsonites are generally associated with anorthosite intrusions and scarce worldwide. [7] Nelsonite occurs at various localities, not limited to: Nelson, Amherst, & Roanoke Counties, Va.; Carthage & Cheney Pond, N.Y.; Laramie, W.Va.; Washington State; Quebec, Canada; and China.[3]

Roseland-Piney River district, Virginia

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The nelsonite occurs in alkalic Roseland anorthosite, and in gneiss, granulite, and charnockitic rocks surrounding the anorthosite. Multiple varieties of equigranular nelsonite are present in the Roseland-Piney River district.[1]

  • Ilmenite nelsonite: the most abundant variety, commonly occurs in marginal parts of the anorthosite and in surrounding rocks near the anorthosite contact.
  • rutile nelsonite: occurs only within the anorthosite.
  • magnetite and biotite nelsonite: limited to the rocks surrounding the Roseland anorthosite.
  • hornblende nelsonite
  • gabbro-nelsonite: a rock intermediate in composition between gabbro and nelsonite

The prefixes ilmenite, rutile, magnetite, biotite, and hornblende denote special richness of the rocks in these minerals.[1]

References

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  1. ^ a b c d e Watson, Thomas; Taber, Stephen (1913). Bulletin 003-A, Geology of the Titanium and Apatite Deposits of Virginia (Report). Virginia Geological Survey. Retrieved 2022-04-22.
  2. ^ a b Kolker, Allan (1982). "Mineralogy and Geochemistry of Fe-Ti Oxide and Apatite (Nelsonite) Deposits and Evaluation of the Liquid Immiscibility Hypothesis". Economic Geology. 77 (5): 1146–1158. CiteSeerX 10.1.1.918.2121. doi:10.2113/gsecongeo.77.5.1146.
  3. ^ a b c "Nelsonite State Rock Initiative". Piedmont Virginia Community College. Retrieved 2016-09-14.
  4. ^ "SB 352 Nelsonite; designating as state rock, etc". State of Virginia. Retrieved 2016-05-11.
  5. ^ Johnson, Stanley (August 1964). Iron and Titanium Mineral Pigments in Virginia (PDF) (Report). Virginia Division of Mineral Resources. Retrieved 2022-04-22.
  6. ^ a b c d "Virginia's State Rock: Nelsonite". William & Mary University. Retrieved 2022-04-20.
  7. ^ a b c d "Origin of nelsonite and Fe–Ti oxides ore of the Damiao anorthosite complex, NE China: Evidence from trace element geochemistry of apatite, plagioclase, magnetite and ilmenite". Ore Geology Reviews. Retrieved 2022-04-18.
  8. ^ Herz, Norman; Force, Eric (1987). "Geology and Mineral Deposits of the Roseland District of Central Virginia" (PDF). USGS. 1371: 4. doi:10.3133/pp1371.