3D model (JSmol)
|Molar mass||136.24 g/mol|
|Appearance||Colorless oil (α and β)|
|Density||α: 0.846 g/cm3|
β: 0.85 g/cm3
|Boiling point||α: 171-172 °C|
β: 171-172 °C
|Insoluble (α and β)|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Phellandrene is the name for a pair of organic compounds that have a similar molecular structure and similar chemical properties. α-Phellandrene and β-phellandrene are cyclic monoterpenes and are double-bond isomers. In α-phellandrene, both double bonds are endocyclic and in β-phellandrene, one of them is exocyclic. Both are insoluble in water, but miscible with ether.
α-Phellandrene was named after Eucalyptus phellandra, now called Eucalyptus radiata, from which it can be isolated. It is also a constituent of the essential oil of Eucalyptus dives. β-Phellandrene has been isolated from the oil of water fennel and Canada balsam oil.
The phellandrenes are used in fragrances because of their pleasing aromas. The odor of β-phellandrene has been described as peppery-minty and slightly citrusy.
The α-phellandrene isomer can form hazardous and explosive peroxides on contact with air at elevated temperatures.
- The Merck Index, 12th Edition, 7340, 7341
- Jacobs, S.W.L., Pickard, J., Plants of New South Wales, 1981, ISBN 0-7240-1978-2.
- Boland, D.J., Brophy, J.J., and A.P.N. House, Eucalyptus Leaf Oils, 1991, ISBN 0-909605-69-6.
- Urben, Peter (2007). Bretherick's Handobook of Reactive Chemical Hazards. 1 (7 ed.). Butterworth-Heinemann. p. 1154.