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Phosphorus heptabromide

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Phosphorus heptabromide
Skeletal formula of phosphorus heptabromide
Space-filling models of the ions in phosphorus heptabromide
Names
Other names
Tetrabromophosphonium tribromide
Perbromophosphonium tribromide
Phosphorus heptabromide
Identifiers
3D model (JSmol)
  • Br[P+](Br)(Br)Br.Br[Br-]Br
Properties
Br7P
Molar mass 590.302 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Phosphorus heptabromide is an inorganic compound with the formula PBr7. It is one of the phosphorus bromides. At normal conditions, it forms red prismatic crystals. PBr7 can be prepared by the sublimation of a mixture of phosphorus pentabromide and bromine.[1]

The structure consists of the PBr4+ cation paired with a tribromide (Br3) anion.[2]

See also

References

  1. ^ T. E. (Thomas Edward) Thorpe. A dictionary of applied chemistry (Volume 4)
  2. ^ Breneman, G. L.; Willett, R. D. (1967). "The crystal structure of phosphorus heptabromide, PBr7". Acta Crystallographica. 23 (3): 467–471. doi:10.1107/S0365110X67002981.