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Stemar-13-ene synthase

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Stemar-13-ene synthase
Identifiers
EC no.4.2.3.33
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
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Stemar-13-ene synthase (EC 4.2.3.33, OsDTC2, OsK8, OsKL8, OsKS8, stemarene synthase, syn-stemar-13-ene synthase) is an enzyme with systematic name 9alpha-copalyl-diphosphate diphosphate-lyase (stemar-13-ene-forming).[1][2] This enzyme catalyses the following chemical reaction

9alpha-copalyl diphosphate stemar-13-ene + diphosphate

This diterpene cyclase produces stemar-13-ene, a putative precursor of the rice phytoalexin oryzalexin S.

References

  1. ^ Mohan, R.S., Yee, N.K., Coates, R.M., Ren, Y.Y., Stamenkovic, P., Mendez, I. and West, C.A. (1996). "Biosynthesis of cyclic diterpene hydrocarbons in rice cell suspensions: conversion of 9,10-syn-labda-8(17),13-dienyl diphosphate to 9β-pimara-7,15-diene and stemar-13-ene". Arch. Biochem. Biophys. 330: 33–47. doi:10.1006/abbi.1996.0223. PMID 8651702.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Nemoto, T., Cho, E.M., Okada, A., Okada, K., Otomo, K., Kanno, Y., Toyomasu, T., Mitsuhashi, W., Sassa, T., Minami, E., Shibuya, N., Nishiyama, M., Nojiri, H. and Yamane, H. (2004). "Stemar-13-ene synthase, a diterpene cyclase involved in the biosynthesis of the phytoalexin oryzalexin S in rice". FEBS Lett. 571 (1–3): 182–186. doi:10.1016/j.febslet.2004.07.002. PMID 15280039.{{cite journal}}: CS1 maint: multiple names: authors list (link)