Uranium tetrafluoride

Uranium tetrafluoride

Names
IUPAC names Uranium(IV) fluoride Uranium tetrafluoride
Identifiers
CAS Number	10049-14-6 Y
3D model (JSmol)	Interactive image
ChemSpider	14676181 Y
ECHA InfoCard	100.030.142
CompTox Dashboard (EPA)	DTXSID30892258
InChI InChI=1S/4FH.2U/h4*1H;;/q;;;;2*+2/p-4 Y Key: CWWZGQYYTNZESQ-UHFFFAOYSA-J Y InChI=1/4FH.2U/h4*1H;;/q;;;;2*+2/p-4 Key: CWWZGQYYTNZESQ-XBHQNQODAW
SMILES [U+2].[U+2].[F-].[F-].[F-].[F-]
Properties
Chemical formula	UF4
Molar mass	314.02 g/mol
Appearance	Green crystalline solid.
Density	6.70 g/cm3, solid.
Melting point	1,036 °C (1,897 °F; 1,309 K)
Boiling point	1,417 °C (2,583 °F; 1,690 K)
Solubility in water	Insoluble.
Structure
Crystal structure	Monoclinic, mS60
Space group	C2/c, No. 15
Hazards
Flash point	Non-flammable
Safety data sheet (SDS)	External MSDS
Related compounds
Other anions	Uranium(IV) chloride Uranium(IV) bromide Uranium(IV) iodide Uranium dioxide
Other cations	Thorium(IV) fluoride Protactinium(IV) fluoride Neptunium(IV) fluoride Plutonium(IV) fluoride
Related compounds	Uranium hexafluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y verify (what is YN ?) Infobox references

Uranium tetrafluoride (UF₄) is a green crystalline solid compound or a salty form of uranium with an insignificant vapor pressure and very slight solubility in water. Uranium in its tetravalent (uranous) state is very important in different technological processes. In the uranium refining industry it is known as green salt.

UF₄ is generally an intermediate in the conversion of uranium hexafluoride (UF₆) to either uranium oxides (U₃O₈ or UO₂) or uranium metal. It is formed by the reaction of UF₆ with hydrogen gas in a vertical tube-type reactor or by the action of hydrogen fluoride (HF) on uranium dioxide. UF₄ is less stable than the uranium oxides and reacts slowly with moisture at ambient temperature, forming UO₂ and HF, the latter of which is very corrosive; it is thus a less favorable form for long-term disposal. The bulk density of UF₄ varies from about 2.0 g/cm³ to about 4.5 g/cm³ depending on the production process and the properties of the starting uranium compounds.

A molten salt reactor design, a type of nuclear reactor where the working fluid is a molten salt, would use UF₄ as the core material. UF₄ is generally chosen over other salts because of the usefulness of the elements without isotope separation, better neutron economy and moderating efficiency, lower vapor pressure and better chemical stability.

Like all uranium salts UF₄ is toxic and thus harmful by inhalation, ingestion and through skin contact.

References

• Booth, H. S.; Krasny-Ergen, W.; Heath, R. E. (1946). "Uranium Tetrafluoride". Journal of the American Chemical Society. 68 (10): 1969. doi:10.1021/ja01214a028.
• Kern, S.; Hayward, J.; Roberts, S.; Richardson, J. W.; Rotella, F. J.; Soderholm, L.; Cort, B.; Tinkle, M.; West, M.; Hoisington, D.; Lander, G. A. (1994). "Temperature Variation of the Structural Parameters in Actinide Tetrafluorides". The Journal of Chemical Physics. 101 (11): 9333–9337. Bibcode:1994JChPh.101.9333K. doi:10.1063/1.467963.

External links

• "Uranium Tetrafluoride". Appendix A of the PEIS (DOE/EIS-0269). Argonne National Laboratory. Retrieved 22 November 2011. {{cite web}}: Cite has empty unknown parameter: |month= (help)