User:Graeme Bartlett/selenite chloride
A selenite chloride is a chemical compound or salt that contains chloride and selenite anions (Cl− and (SeO2-
3). These are mixed anion compounds. Some have third anions, including nitrate (NO−3), molybdate (MoO4), oxalate (C
2O2−
4), selenate (SeO2−
4), silicate (SiO2−
4) and tellurate (TeO2−
4).
Naming[edit]
A selenite chloride compound may also be called a chloride oxoselenate(IV) using IUPAC naming for inorganic compounds.
Production[edit]
Rare earth selenite chlorides can be produced by dissolving the rare earth selenate
Related[edit]
Related to these are the selenite fluorides and selenite bromides by varying the halogenide. Similar compounds by varying the chalcogen also include the sulfite chlorides and tellurite chlorides.
List[edit]
| name | formula | ratio
SeO3:Cl |
mw | system | space group | unit cell Å | volume | density | optical | references |
|---|---|---|---|---|---|---|---|---|---|---|
| scandium selenite fluoride | ScSeO3F | 1:1 | triclinic | P1 <13 | −173°C a=6.2769 b=6.5578 c=4.0627 α=95.478 β=95.332 γ=92.363 Z=2 | |||||
| monoclinic | P21/m >13 | [1] | ||||||||
| RbCl·(H2SeO3)2 | 2:1 | triclinic | P1 | a=5.2240 b=6.3562 c=6.4079 α=72.940° β=89.697° γ=78.066° | UV cut off 230 nm; birefringence 0.14 at 589 nm | [2] | ||||
| Pb2Bi(SeO3)2Cl3 | 2:3 | monoclinic | C2 | a=13.2270 b=5.6002 c=7.7021, β=115.070° | SHG 13.5×KDP; band gap 3.45 eV | [3] |
References[edit]
- ^ Cite error: The named reference
:2was invoked but never defined (see the help page). - ^ Wang, Huan; Liu, Lili; Hu, Zhaowei; Wang, Junbo; Zhu, Mengmeng; Meng, Yu; Xu, Jiayue (2023-01-09). "RbCl·(H 2 SeO 3 ) 2 : A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence". Inorganic Chemistry. 62 (1): 557–564. doi:10.1021/acs.inorgchem.2c03787. ISSN 0020-1669.
- ^ Jia, Ying-Jie; Zhang, Xingyu; Chen, Yi-Gang; Jiang, Xingxing; Song, Jia-Neng; Lin, Zheshuai; Zhang, Xian-Ming (2022-10-03). "PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties". Inorganic Chemistry. 61 (39): 15368–15376. doi:10.1021/acs.inorgchem.2c01802. ISSN 0020-1669.