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User:OrganoMetallurgy/Drafts/closo-Azadodecaborane

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OrganoMetallurgy/Drafts/closo-Azadodecaborane
Identifiers
Properties
B11H12N
Molar mass 145.01 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

non-chembox sections

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closo-Azadodecaborane is a heteroborane/azaborane notable for having six-coordinate nitrogen.

Structure and bonding

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Distorted icosahedral structure with exopolyhedral bonds to hydrogen and the bonds surrounding the nitrogen are shorter. NH contributes four electrons to the framework bonding something something has 2n+2 electrons contributing to bonding so it's a closo cluster something something Wade's rules something something.

Synthesis

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nido-azaundecaborane(12) anion (NB10H12) and BH3

Reactions

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Applications

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References

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