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William Clyde Martin Jr.

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William Clyde Martin Jr.
William Clyde Martin Jr. (1929–2013).
BornNovember 27, 1929
Cullman, Alabama
DiedSeptember 15, 2013(2013-09-15) (aged 83)
Washington, D.C.
NationalityAmerican
Alma materUniversity of Richmond (B.S.)
Princeton University (Ph.D.)
AwardsDepartment of Commerce Silver Medal (1968), Department of Commerce Gold Medal (1981), William F. Meggers Award (1983), Allen V. Astin Measurement Science Award (1992)
Scientific career
FieldsAtomic spectroscopy
InstitutionsNational Bureau of Standards, National Institute of Standards and Technology
Doctoral advisorAllen Shenstone

William Clyde Martin Jr. (November 27, 1929 – September 15, 2013) was an American physicist. After receiving his Ph.D. degree from Princeton University in 1956, he joined the staff of the National Bureau of Standards (NBS: now NIST, the National Institute of Standards and Technology), where he was employed until his retirement in 1998. As Chief of the NBS Atomic Spectroscopy Section (and its successor organizations) from 1962 to 1998, he led the development of its reference data resources on the spectra of rare-earth elements, substantially increased its coverage of highly excited and ionized species, and pioneered the publication of NIST Standard Reference Data on the internet.

Life

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Martin was in born in Cullman, Alabama on November 27, 1929. He received a B.S. in physics from the University of Richmond in 1951 and then pursued graduate studies at Princeton University, where he received a Ph.D. in physics after completing a doctoral dissertation, titled "The energy levels and spectra of neutral and singly ionized phosphorus", under the supervision of Allen G. Shenstone.[1] As a student at Princeton, he had some encounters with Albert Einstein, who lived near his lodgings. Martin served as an instructor in physics at Princeton during 1955–1957. In 1957 he was hired as a physicist by the National Bureau of Standards, where he spent the rest of his career, retiring in 1998 and remaining active as an emeritus member of staff until his death in 2013.

In 1959 he married Dolores Moyano. They had two sons, Eric B. Martin and Christian B. Martin.

Scientific contributions

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In 1962, Martin was appointed chief of the NBS Atomic Spectroscopy Section (later renamed the Atomic Spectroscopy Group), and his most influential work was done in that capacity and during his subsequent leadership of its successor organizations until 1998.

The generation, curation and publication of critically evaluated data on atomic energy levels was a major scientific activity of NBS when Martin joined its staff.

That program had resulted in the publication of three landmark monographs[2][3][4] Widely known in the spectroscopy community as Charlotte Moore's tables, these monographs, which have been cited over 10,000 times in the scientific literature, tabulated the energies and other properties of atomic energy levels of the elements from hydrogen (atomic number Z = 1) through actinium (atomic number Z = 89), except for the rare-earth elements, cerium (atomic number Z = 58) through lutetium (atomic number Z = 71).

Martin began a long project of analysis of the spectra of the rare earths that resulted in numerous research publications and a fourth monograph,[5] that completed the NBS coverage of the periodic table up to the actinide series. In 1963, he established[6] that the ground level of atomic cerium is of the form 6s25d4f 1G4°, in standard notation.[7] At the time, it was widely believed that the ground electronic configuration of this element was 6s24f2, an error that could still be found in reference sources fifty years later.[8]

In the 1970s and 1980s, basic scientific advances, such as laser and plasma spectroscopy, and user needs, particularly those of the nuclear fusion and astrophysics communities, were generating vast quantities of new atomic spectral data and additional data needs, notably those associated with highly excited or ionized species. Martin and his co-workers initiated analyses that covered data from all ions of most second-row elements in the periodic table:

The culminating effort of this period was a major atomic spectral compilation,[15] issued in print by NBS in 1985 under Martin's supervision: a 664-page compilation of all data known then, for all ionization stages of the elements potassium (atomic number Z = 19) through nickel (atomic number Z = 28).

At that time it was clear that the vast expansion of atomic data could no longer be adequately disseminated by print publications alone. Many NIST data publications had been converted to magnetic storage media, which could be purchased from the NIST Standard Reference Data Program. In the early 1990s, perceiving the potential of the World Wide Web, Martin persuaded NIST management to allow free distribution of NIST atomic data on the internet. This was the first foray of NIST into free online data distribution, which remains in place today and has since been followed by other NIST data resources.

The most comprehensive of the NIST atomic data products is the NIST Atomic Spectra Database (ASD).[16] First placed online in March, 1995, it was serving about 60,000 page requests per month in late 2013. In addition to his many contributions to ASD, Martin was coauthor of The Handbook of Basic Atomic Spectroscopic Data,[17] which contains data on spectra of neutral atoms and singly charged ions of all elements from hydrogen through einsteinium (atomic number Z = 99). He was also the architect of the NIST Periodic Table: Atomic Properties of the Elements,[18] which has had over 100,000 copies distributed in its print version as of 2013.

Another of Martin's abiding concerns was the accurate description of the spectrum of atomic helium. This spectrum is of particular importance as a calibration reference, a benchmark for theoretical calculations of atomic structure and of quantum electrodynamics effects in atoms, and for applications in astrophysics. Martin's publications on this spectrum, beginning in his early years at NBS and spanning five decades,[19][20][21][22][23][24][25][26] remain the definitive sources of reference data as of 2013.

Honors

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Obituaries

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  • Barnes, Bart (15 October 2013). "William C. Martin, National Institute of Standards and Technology scientist, dies at 83". The Washington Post. Retrieved 7 January 2014.
  • Reader, Joseph; Lide, David R. (2013). "William C. Martin". Physics Today. doi:10.1063/pt.5.6025.
  • "In Memoriam: William C. Martin, OSA Fellow Emeritus, 1929–2013". The Optical Society. 2013. Retrieved 7 January 2014.
  • Reader, Joseph; Lide, David R. (2013). "William C. Martin (1929–2013)". American Astronomical Society. Retrieved 7 January 2014.

References

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  1. ^ Martin, W. C. (1956). The energy levels and spectra of neutral and singly ionized phosphorus.
  2. ^ Moore, Charlotte E. (1949). Atomic energy levels as derived from the analyses of optical spectra. Vol. 1. Washington, D.C.: U.S. Government Printing Office.
  3. ^ Moore, Charlotte E. (1952). Atomic energy levels as derived from the analyses of optical spectra. Vol. 2. Washington, D.C.: U.S. Government Printing Office.
  4. ^ Moore, Charlotte E. (1958). Atomic energy levels as derived from the analyses of optical spectra. Vol. 3. Washington, D.C.: U.S. Government Printing Office.
  5. ^ Martin, W. C.; Zalubas, Romuald; Hagan, Lucy (1978). Atomic energy levels - The rare-earth elements. Washington, D.C.: U.S. Government Printing Office. Bibcode:1978aelr.book.....M.
  6. ^ Martin, W. C. (1963). "Low Energy Levels of Neutral Cerium (Ce I)". J. Opt. Soc. Am. 5 (9): 1047. Bibcode:1963JOSA...53.1047M. doi:10.1364/JOSA.53.001047.
  7. ^ Martin, W. C.; Wiese, W. L. (2006). "Chapter 10: Atomic Spectroscopy". In Drake, G. W. F. (ed.). Springer Handbook of Atomic, Molecular and Optical Physics. Springer. pp. 175–198. ISBN 978-0-387-20802-2.
  8. ^ "cerium (Ce)". Encyclopædia Britannica. 2012-10-02. Retrieved 2014-01-08.
  9. ^ Martin, W. C.; Zalubas, Romuald (1981). "Energy levels of Sodium, Na I through Na XI". J. Phys. Chem. Ref. Data. 10 (1): 153. Bibcode:1981JPCRD..10..153M. doi:10.1063/1.555637. S2CID 96405107.
  10. ^ Martin, W. C.; Zalubas, Romuald (1980). "Energy levels of Magnesium, Mg I through Mg XII". J. Phys. Chem. Ref. Data. 9 (1): 1. Bibcode:1980JPCRD...9....1M. doi:10.1063/1.555617. S2CID 95690896.
  11. ^ Martin, W. C.; Zalubas, Romuald (1979). "Energy levels of Aluminum, Al I through Al XIII". J. Phys. Chem. Ref. Data. 8 (3): 817. Bibcode:1979JPCRD...8..817M. doi:10.1063/1.555608. S2CID 96058180.
  12. ^ Martin, W. C.; Zalubas, Romuald (1983). "Energy levels of Silicon, Si I through Si XIV". J. Phys. Chem. Ref. Data. 12 (2): 323. Bibcode:1983JPCRD..12..323M. doi:10.1063/1.555685.
  13. ^ Martin, W. C.; Zalubas, Romuald; Musgrove, Arlene (1985). "Energy levels of Phosphorus, P I through P XV". J. Phys. Chem. Ref. Data. 14 (3): 751. Bibcode:1985JPCRD..14..751M. doi:10.1063/1.555736. S2CID 95776698.
  14. ^ Martin, W. C.; Zalubas, Romuald; Musgrove, Arlene (1990). "Energy levels of Sulfur, S I through S XVI". J. Phys. Chem. Ref. Data. 19 (4): 821. Bibcode:1990JPCRD..19..821M. doi:10.1063/1.555862.
  15. ^ Sugar, Jack; Corliss, Charles (1985). "Atomic Energy Levels of the Iron-Period Elements: Potassium through Nickel" (PDF). J. Phys. Chem. Ref. Data. 14, Supp. 2, pp. 1 - 664. Bibcode:1985aeli.book.....S.
  16. ^ "Atomic Spectra Database". National Institute of Standards and Technology. March 1995. Retrieved 2014-01-02.
  17. ^ Sansonetti, J. E.; Martin, W. C. (March 2003). "The Handbook of Basic Atomic Spectroscopic Data". National Institute of Standards and Technology. Retrieved 2014-01-02.
  18. ^ Dragoset, R. A.; Musgrove, A.; Clark, C. W.; Martin, W. C. (2009-07-30). "Periodic Table: Atomic Properties of the Elements". NIST Special Publication 966. National Institute of Standards and Technology. Retrieved 2014-01-07.
  19. ^ Martin, W. C. (1959). "Energy Levels and Spectrum of Neutral Helium (4He I)". Journal of Research of the National Bureau of Standards Section A. 64 (1): 19–28. doi:10.6028/jres.064A.003. PMC 5287023. PMID 32196153.
  20. ^ Martin, W. C. (1973). "Energy Levels of Neutral Helium (4He I)". J. Phys. Chem. Ref. Data. 2 (2): 257. Bibcode:1973JPCRD...2..257M. doi:10.1063/1.3253119. S2CID 98503282.
  21. ^ Martin, W. C.; Sansonetti, Craig J. (1983). "Improved measurement of the 4He I 31D - 33D separation: Confirmation of predicted mass-polarization isotopic shift". Phys. Rev. A. 28 (1): 502. Bibcode:1983PhRvA..28..502M. doi:10.1103/PhysRevA.28.502.
  22. ^ Sansonetti, Craig J.; Martin, W. C. (1984). "Accurate wave-number measurements for the 4He I 1s2p - 1s3d transitions and comparisons of several term separations with theory". Phys. Rev. A. 29 (1): 159. Bibcode:1984PhRvA..29..159S. doi:10.1103/PhysRevA.29.159.
  23. ^ Martin, W. C. (1984). "New values for some 4He I 1snl energy levels, ionization energies, and Lamb shifts". Phys. Rev. A. 29 (4): 1883. Bibcode:1984PhRvA..29.1883M. doi:10.1103/PhysRevA.29.1883.
  24. ^ Martin, W. C. (1987). "Improved 4He I 1snl ionization energy, energy levels, and Lamb shifts for 1sns and 1snp terms". Phys. Rev. A. 36 (8): 3575–3589. Bibcode:1987PhRvA..36.3575M. doi:10.1103/PhysRevA.36.3575. PMID 9899293.
  25. ^ Sims, James S.; Martin, W. C. (1988). "Variational calculations for 4He I: Improved energies for singlet and triplet nD and nF levels (n = 3 - 8)". Phys. Rev. A. 37 (7): 2259–2269. Bibcode:1988PhRvA..37.2259S. doi:10.1103/PhysRevA.37.2259. PMID 9899927.
  26. ^ Drake, W. C.; Martin, W.C. (1998). "Ionization energies and quantum electrodynamic effects in the lower 1sns and 1snp levels of neutral helium (4He I)". Can. J. Phys. 76 (9): 679. Bibcode:1998CaJPh..76..679D. doi:10.1139/cjp-76-9-679.
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