Phosphoric acid fuel cell
Phosphoric acid fuel cells (PAFC) are a type of fuel cell that uses liquid phosphoric acid as an electrolyte. They were the first fuel cells to be commercialized. Developed in the mid-1960s and field-tested since the 1970s, they have improved significantly in stability, performance, and cost. Such characteristics have made the PAFC a good candidate for early stationary applications.
Electrolyte is highly concentrated or pure liquid phosphoric acid (H3PO4) saturated in a silicon carbide matrix (SiC). Operating range is about 150 to 210 °C. The electrodes are made of carbon paper coated with a finely dispersed platinum catalyst.
Anode reaction: 2H₂ → 4H+ + 4e‾
Cathode reaction: O₂(g) + 4H+ + 4e‾ → 2H₂O
Overall cell reaction: 2 H₂ + O₂ → 2H₂O
Advantages and disadvantages
At an operating range of 150 to 200 °C, the expelled water can be converted to steam for air and water heating (combined heat and power). This potentially allows efficiency increases of up to 70%. PAFCs are CO2-tolerant and even can tolerate a CO concentration of about 1.5 percent, which broadens the choice of fuels they can use. If gasoline is used, the sulfur must be removed. At lower temperatures phosphoric acid is a poor ionic conductor, and CO poisoning of the platinum electro-catalyst in the anode becomes severe. However, they are much less sensitive to CO than PEFCs and AFCs.
Disadvantages include rather low power density and aggressive electrolyte.[clarification needed]
PAFC have been used for stationary power generators with output in the 100 kW to 400 kW range and they are also finding application in large vehicles such as buses.
Major manufacturers of PAFC technology include ClearEdge Power (formerly UTC Power) and Fuji Electric. India's DRDO are developing PAFC for air independent propulsion in their Scorpène class submarines, and the Indian Navy have requested a fully engineered system by 2014.
- Types - Phosphoric Acid Fuel Cells
- Fuel Cells
- Fuel Cells 2000 : Fuel Cell Basics : Types
- Fuel Cell Today - Home Page
- Anandan, S. (30 December 2010). "DRDO working on system to cut submarine vulnerability". The Hindu.
- National Pollutant Inventory - Phosphoric acid fact sheet
- UTC Power Official Site
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- Cox Communications Installs Fuel Cells in California
- D.O.E. -PAFC
- Fuel Cell Basics
- Alternative Energy Magazine
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