Heavy liquid
{{About|chemicals|the music album|Heavy Liquid|comic used for determination of density in mineralogy, for density gradient centrifugation and for separating mixtures.
Uses
Common applications of heavy liquids include:
- Density gradient centrifugation
- Separating mixtures and sink/swim analysis
- Flotation process
- Determination of density
Toxicity
The classical heavy liquids like 1,1,2,2-tetrabromoethane (Muthmanns solution), potassium tetraiodomercurate(II) (Thoulets solution), bromoform or diiodomethane which are used in mineralogy are very toxic. These toxic chemicals are avoided today in consideration of the fact that there are alternative water based, non-toxic heavy liquids like sodium polytungstate solutions.[1] With this relatively new heavy liquid densities up to 3.1 g·cm−3 can be adjusted . Adding parts of pulverulent Tungsten carbide increases the density to 4.6 g·cm−3.[2]
List of common heavy liquids with density > 2.0 g·cm−3
| Name | Density in g·cm−3 |
|---|---|
| 1,2-Dibromoethane | 2.180 |
| cis-1,2-Dibromoethene | 2.246 |
| trans-1,2-Dibromoethene | 2.231 |
| Dibromomethane | 2.477 |
| Bromal | 2.550 |
| Bromoform | 2.890 |
| 1,1,2,2-Tetrabromoethane (Muthmanns solution) | 2.967 |
| Sodium polytungstate | 3.100 |
| Bromine | 3.1028 |
| Thoulets solution | 3.196 |
| Diiodomethane | 3.325 |
| Indiumiodide | 3.40 |
| Bariummercuriciodide | 3.57 |
| Thallium formate + Thallium malonate (Clerici solution) | 4.25 |
| Liquid metal (Gallium/Indium/Tin/Zinc alloy) | 6.5 |
| Mercury | 13.6 |
References
Literature
- Schnitzer W, Zur Problematik der Schwermineralanalyse am Beispiel triassischer Sedimentgesteine, in International Journal of Earth Sciences, 72/1983, S.67–75, ISSN 1437-3254 (Print) 1437-3262 (Online)
- Boenigk, Schwermineralanalyse, S.6–15, Stuttgart: Enke, 1983.
- Ney, Gesteinsaufbereitung im Labor, S.92–113, Stuttgart: Enke, 1986.
External links
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