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Potassium amyl xanthate

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Potassium amyl xanthate
Names
IUPAC name
potassium O-pentylcarbonodithioate
Other names
potassium pentylxanthogenate
potassium-O-pentyl dithiocarbonate
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.018.481 Edit this at Wikidata
EC Number
  • 220-329-5
  • InChI=1S/C6H12OS2.K/c1-2-3-4-5-7-6(8)9;/h2-5H2,1H3,(H,8,9);/q;+1/p-1 checkY
    Key: YIBBMDDEXKBIAM-UHFFFAOYSA-M checkY
  • InChI=1S/C6H12OS2.K/c1-2-3-4-5-7-6(8)9;/h2-5H2,1H3,(H,8,9);/q;+1/p-1
  • CCCCCOC(=S)[S-].[K+]
Properties
C6H11KOS2
Molar mass 202.37 g·mol−1
Appearance Pale yellow or yellow free flowing powder
Density 1.073 g/cm
Soluble
Hazards
GHS labelling:
GHS02: FlammableGHS07: Exclamation markGHS09: Environmental hazard
Warning
H228, H302, H312, H315, H319, H335, H411
P210, P240, P241, P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P391, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium amyl xanthate is an organosulfur compound with the chemical formula CH3(CH2)4OCS2K. It is a pale yellow powder or pellet with a pungent odor, soluble in water. It is widely used in the mining industry for the separation of ores using the flotation process.

Production and properties

Potassium amyl xanthate is prepared by reacting amyl alcohol with carbon disulfide and potassium hydroxide.[1]

CH3(CH2)4OH + CS2 + KOH → CH3(CH2)4OCS2K + H2O

Potassium amyl xanthate is a pale yellow powder that is relatively stable between pH 8 and 13 with a maximum of stability at pH 10.[2]

Safety

The LD50 is 480 mg/kg (oral, rats) for potassium pentylxanthate.[3]

It is a biodegradable compound.

References

  1. ^ Charles C. Price and Gardner W. Stacy (1948). "p-nitrophenyl) sulfide". Organic Syntheses. 28: 82; Collected Volumes, vol. 3, p. 667.
  2. ^ J. Dyer, L. H. Phifer, Macromolecules 2 (1969) 111. R. J. Millican, C. K. Sauers, J. Org. Chem. 44 (1979) 1964.
  3. ^ Kathrin-Maria Roy "Xanthates" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim.