Caesium monoxide
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| Names | |
|---|---|
| IUPAC name
Caesium oxide
| |
| Other names
Cesium oxide (US)
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.039.693 |
| EC Number |
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PubChem CID
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| Properties | |
| Cs2O | |
| Molar mass | 281.81 g/mol |
| Appearance | yellow-orange solid |
| Density | 4.65 g/cm3, solid |
| Melting point | 490 °C (914 °F; 763 K) (under N2) |
| reacts violently to form CsOH | |
| Structure | |
| anti-CdCl2 (hexagonal) | |
| Thermochemistry | |
Heat capacity (C)
|
76.0 J K−1 mol−1 |
Std molar
entropy (S⦵298) |
146.9 J K−1 mol−1 |
Std enthalpy of
formation (ΔfH⦵298) |
-345.8 kJ/mol |
| Hazards | |
| Flash point | non-flammable |
| Related compounds | |
Other anions
|
Caesium hydroxide |
Other cations
|
Lithium oxide Sodium oxide Potassium oxide Rubidium oxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Caesium oxide (IUPAC name) or cesium oxide describes inorganic compounds composed of caesium and oxygen. The following binary (containing only Cs and O) oxides of caesium are known: Cs11O3, Cs4O, Cs7O, and Cs2O.[3] Both the oxide and suboxides are brightly coloured. The species Cs2O forms yellow-orange hexagonal crystals.[1]
Uses
Caesium oxide is used in photocathodes to detect infrared signals in devices such as image intensifiers, vacuum photodiodes, photomultipliers, and TV camera tubes[4] L. R. Koller described the first modern photoemissive surface in 1929–30 as a layer of caesium on a layer of caesium oxide on a layer of silver.[5] It is a good electron emitter; however, its high vapor pressure limits its usefulness.[6]
Reactions
Elemental magnesium reduces caesium oxide to elemental caesium, forming magnesium oxide as a side-product:[7][8]
- Cs2O + Mg → 2Cs + MgO
Cs2O is hygroscopic, forming the corrosive CsOH on contact with water.
References
- ^ a b Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. pp. 451, 514. ISBN 0-8493-0487-3..
- ^ Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. pp. 97–100. ISBN 978-0-08-022057-4..
- ^ Simon, A. (1997), "Group 1 and 2 Suboxides and Subnitrides — Metals with Atomic Size Holes and Tunnels", Coord. Chem. Rev., 163: 253–270, doi:10.1016/S0010-8545(97)00013-1.
- ^ Capper, Peter; Elliott, C. T. (2000), Infrared Detectors and Emitters, Springer, p. 14, ISBN 978-0-7923-7206-6
- ^ Busch, Kenneth W.; Busch, Marianna A. (1990), Multielement Detection Systems for Spectrochemical Analysis, Wiley-Interscience, p. 12, ISBN 978-0-471-81974-5
- ^ Boolchand, Punit, ed. (2000), Insulating and Semiconducting Glasses, World Scientific, p. 855, ISBN 978-981-02-3673-1
- ^ Turner, Jr., Francis M., ed. (1920), The Condensed Chemical Dictionary, New York: Chemical Catalog Co., p. 121
- ^ Arora, M.G. (1997), S-Block Elements, New Delhi: Anmol Publications, p. 13, ISBN 978-81-7488-562-3
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