Jump to content

Calcium tartrate

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by 66.19.93.154 (talk) at 08:46, 27 May 2016 (ref for solubility is US patent 3114770; more acid is found in unripe grapes). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Calcium tartrate
Names
IUPAC name
2,3-Dihydroxybutanedioic acid calcium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.019.656 Edit this at Wikidata
E number E354 (antioxidants, ...)
  • InChI=1S/C4H6O6.Ca/c5-1(3(7)8)2(6)4(9)10;/h1-2,5-6H,(H,7,8)(H,9,10);/q;+2/p-2 checkY
    Key: GUPPESBEIQALOS-UHFFFAOYSA-L checkY
  • InChI=1/C4H6O6.Ca/c5-1(3(7)8)2(6)4(9)10;/h1-2,5-6H,(H,7,8)(H,9,10);/q;+2/p-2
    Key: GUPPESBEIQALOS-NUQVWONBAP
  • [Ca+2].O=C([O-])C(O)C(O)C([O-])=O
Properties
CaC4H4O6
Molar mass 190.16484 g/mol (anhydrous)
260.21 g/mol (tetrahydrate)
Appearance hygroscopic white powder
or colorless crystals
Density 1.817 g/cm3 (tetrahydrate)
Melting point tetrahydrate decomposes at 160 °C
anhydrous decomposes at 650 °C
0.037 g/100 ml (0 °C) 0.2 g/100 ml (85 °C)
Structure
d or l rhombic
dl triclinic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Calcium tartrate is a byproduct of the wine industry, prepared from wine fermentation dregs. It is the calcium salt of tartaric acid, an acid most commonly found in grapes. Its solubility decreases with lower temperature, which results in the forming of whitish (in red wine often reddish) crystalline clusters as it precipitates. It finds use as a food preservative and acidity regulator. Like tartaric acid, calcium tartrate has two asymmetric carbons, hence it has two chiral isomers and a non-chiral isomer (meso-form). Most calcium tartrate of biological origin is the chiral levorotatory (–) isomer.

References