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Fluoroiodomethane

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This is an old revision of this page, as edited by Emeldir (talk | contribs) at 17:19, 11 September 2016 (preferred IUPAC name (PIN) according to ''Nomenclature of Organic Chemistry – IUPAC Recommendations and Preferred Names 2013 (Blue Book)''). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Fluoroiodomethane
Names
Preferred IUPAC name
Fluoro(iodo)methane
Other names
Fluoroiodomethane
Fluoro-iodo-methane
Fluoromethyl iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.201.539 Edit this at Wikidata
  • InChI=1S/CH2FI/c2-1-3/h1H2 checkY
    Key: XGVXNTVBGYLJIR-UHFFFAOYSA-N checkY
  • InChI=1/CH2FI/c2-1-3/h1H2
  • FCI
Properties
CH2FI
Molar mass 159.93 g/mol
Boiling point 53.4 °C (128.1 °F; 326.5 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Fluoroiodomethane is a mixed halomethane, more exactly fluoroiodocarbon (FIC).

Fluoroiodomethane can be prepared from iodoacetic acid.[1]

Its isotopomer [18F]fluoroiodomethane (PubChem 451313) is a synthetic precursor for fluoromethylation of radiopharmaceuticals.

Also proposal of its use as a safe high-performance foam blowing agent exists.[2]

Notes

References

  • Zheng L.; Berridge M. S. (January 2000). "Synthesis of [18F]fluoromethyl iodide, a synthetic precursor for fluoromethylation of radiopharmaceuticals". Applied Radiation and Isotopes. 52 (1): 55–61(7). doi:10.1016/S0969-8043(99)00061-5. PMID 10670923. Retrieved 2007-06-29.
  • Chin F. T.; Morse Ch. L.; Shetty H. U.; Pike V. W. (December 2005). "Automated radiosynthesis of [18F]SPA-RQ for imaging human brain NK1 receptors with PET". Journal of Labelled Compounds and Radiopharmaceuticals. 49 (1): 17–31(15). doi:10.1002/jlcr.1016. Retrieved 2007-06-29.
  • Tedder, J. M.; Sloan, J. P.; Walton, J. C. (1975). "Free Radical Addition to Olefins, Part XVII. Addition of Fluoroiodomethane to Fluoroethylenes". Journal of the Chemical Society: 1846–1850.