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HIsarna ironmaking process

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The HIsarna ironmaking process is a direct reduced iron process for iron making in which iron ore is processed almost directly into liquid iron (pig iron). The process combines two process units, the Cyclone Converter Furnace (CCF) for ore melting and pre-reduction and a Smelting Reduction Vessel (SRV) where the final reduction stage to liquid iron takes place. The process does not require the manufacturing of iron ore agglomerates such as pellets and sinter, nor the production of coke, which are necessary for the blast furnace process. Without these steps, the HIsarna process is more energy-efficient and has a lower carbon footprint than traditional ironmaking processes.[1][2][3][4] In 2018 Tata Steel announced it has demonstrated that more than 50% CO2 emission reduction is possible with HIsarna technology, without the need for carbon capture technology.[5][6]

The HIsarna process was developed in stages and with pauses at Koninklijke Hoogovens / Corus IJmuiden / Tata Steel IJmuiden, starting in 1986. The final stages were made possible through the Ultra-Low Carbon Dioxide Steelmaking (ULCOS)[7] consortium and cooperation between former Corus (now Tata Steel) and the Rio Tinto Group.[8] The latter contributed their HIsmelt (short for "high intensity smelting") technology[9] to the final design of the installation, prompting the name HIsarna for the process ("HI" from "high intensity" and "sarna" from Isarna, a Celtic word for iron).[4][10][11]

HIsarna is considered one of the most promising developments in reducing CO2 emissions from the steel industry.[12]

History

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The very first attempts at applying cyclone oven technology in the reduction of iron ore took place at Koninklijke Hoogovens in the 1960s. Cyclone technology had already been used successfully in different industrial, chemical processes and designers at Hoogovens thought it might be a strategy for improvement for their process. However, at the time they could not get it to work properly and the experiment was quickly abandoned.[2]

The first serious revival came in 1986, when Hoogovens sought a method of producing steel without having to produce iron ore agglomerates such as pellets and sinter. At that time the desire was mostly a cost-cutting measure in order to make the process cheaper in trying economic times. The trying times did not last however and the project was put on the back burner until the early 1990s.

By the early 1990s the availability of cokes was becoming limited due to many of the major coking facilities in the West that produced cokes from coal reaching the end of their economic life. Heavy environmental restrictions made it unattractive to build new facilities, so steel producers sought ways to reduce the need for cokes; Hoogovens started putting more effort into the cyclone technology as a solution to this problem and a test facility for the cyclone part proved capable of producing twenty tons of pig iron per hour. The rest of the process didn't work very well though,[vague] so when steel producers massively moved to replace part of the coke by powdered coal injection and China started mass-producing cokes, the project lost momentum again. The steep drop in prices of commodities around 1999 caused the project to be halted.[2]

In 2004 however, the European Union brought pressure on the steel industry to reduce its carbon footprint; the ULCOS consortium was founded as a result and in the period 2005–2007 the cyclone technology was selected as one of four high-potential technologies. A theoretical answer was found to the earlier problems of the post-cyclone part of the cyclone furnace in the form of a Smelting Reduction Vessel and the Rio Tinto Group had industrial-scale experience with the required process, called HIsmelt. An agreement between them and ULCOS added the HIsmelt technology to the cyclone furnace and the result was the HIsarna process.[2] In 2017 Tata Steel obtained the smelter IP rights from Rio Tinto, now fully owning all HIsarna IP.[13]

Pilot plant

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External image
image icon HIsarna pilot plant

In 2010 the HIsarna pilot plant was constructed at Tata Steel IJmuiden. The pilot plant has a capacity of producing 65,000 tons of pig iron per year.[10][11] A first campaign of experiments was completed in spring 2011, which was followed by three more successful experimental campaigns. The second and third campaign were co-financed by the Research Fund for Coal and Steel (RFCS).[14] The fourth campaign finished in June 2014. The fifth campaign started in the autumn of 2017.[15][16] This project is part funded by the Horizon 2020 Framework Programme from the EU, as part of the second Sustainable Industry Low Carbon (SILC-II) funding round.[17][18][19]

Process

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External images
image icon Schematic of the HIsarna process (Rio Tinto)[8]
image icon Schematic of the HIsarna process (Tata Steel) [4]
image icon Control room of the HIsarna pilot plant
image icon Cast house and metal tapping at the HIsarna pilot plant
image icon Tapping slag at the HIsarna pilot plant

The HIsarna process is a smelting reduction process with two directly coupled process stages in which the production of liquid pig iron takes place.

It is a combination of a Cyclone Converter Furnace (CCF)[20] which is placed above the Smelting Reduction Vessel (SRV), forming a continuous, once through process. The HIsarna plant is shaped like a wine bottle: a "bottle" at the bottom and a thin "neck" at the top. The geometry of this furnace causes a cyclone to form in the neck when the crushed iron ore is injected into this cyclone together with oxygen (so oxygen is injected at the top rather than at the bottom). The temperature in the cyclone causes a dissociation reaction to take place so that coal, introduced immediately after, reduces iron ore to iron.[2][4]

The molten iron droplets then drip down the furnace wall to the place where the "neck" widens into the "bottle". Here the droplets fall from the wall into the molten slag, which sits on top of the liquid iron bath in the bottom of the furnace. Between the cyclone and the slag layer, oxygen is injected through water cooled lances to generate heat by partly combusting the gases being released from the final reduction reaction step that takes place in the slag. Powder coal is injected into the slag layer, again through water cooled lances. The reduction reaction now continues "as normal" in the bottom of the furnace, with the partially reduced iron ore further reducing to regular pig iron and the whole separating into two molten layers (a top layer of slag and a bottom layer of molten pig iron). Both layers can be tapped individually and the pig iron can be used immediately in the remainder of the basic oxygen steelmaking process.[2][4]

Advantages

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In a technical sense, the advantage of the HIsarna process is that it removes the step of creating iron ore agglomerates and coke to create a porous burden for the blast furnace. In the traditional process one cannot use powdered coal alone since the strength of the coke is required to support the burden. By comparison, in HIsarna, the powder form of the coal and ore are an advantage because the increased surface area improves the speed and quality of the reduction reaction in the cyclone.[2][4]

The main advantages of the process are derived from those mentioned above, however: the fact that the separate steps of creating ore agglomerates and cokes disappear from the process makes the process more energy efficient and reduces its carbon footprint.[2][3][4][10][11] This makes the process attractive to steelmakers, who are being pressured to make their processes more environmentally friendly — particularly in Europe, where government regulations are increasingly attaching a financial penalty to high carbon dioxide emissions. The HIsarna process uses 20% less energy and emits at least 20% less CO2 per ton steel compared to conventional pig iron production.[4][21] Further environmental advantages include a significant reduction of other emissions such as NOx, SOx and fine dust.[22] CO2 emission reductions of more than 50% can be achieved by replacing part of the coal for sustainable biomass and using steel scrap in the process.[5][6]

Besides the direct environmental benefits HIsarna offers economic benefits as well.[22] The process is able to handle low cost ores and coals and has lower investment costs. The hot metal produced in HIsarna also has advantages for the steelmaking process, allowing for lower slag and metal phosphorus levels in the BOF converter or larger hot metal charges in an Electric arc furnace.[23]

Further development

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Tata Steel is also planning to develop the process in such a way that zinc can be recovered,[24] supported by the EIT RawMaterials, and CO2 can be captured for utilisation or storage.[22]

In November 2018 it was announced that a larger-scale HIsarna pilot facility could be built at the Tata Steel site in Jamshedpur, India,[25][26] but that the site in IJmuiden would still be a potential location for further industrial implementation of the technology.[27][28]

See also

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References

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  1. ^ "Revolutionary ironmaking process cuts both carbon and costs". Archived from the original on 27 March 2016. Retrieved 19 March 2016.
  2. ^ a b c d e f g h Van den Brink, Erwin (3 September 2010), "Nieuwe ijzertijd" (PDF), De Ingenieur (in Dutch), vol. 122, no. 13, pp. 50–51, ISSN 0020-1146
  3. ^ a b Meijer, Koen; Borlee, Jean; Skorianz, Michael; Feilmayr, Christoph; Goedert, Paul; Dry, Rod (15 June 2015). HIsarna - Highly energy efficient ironmaking. METEC-ESTAD 2015. Duesseldorf.
  4. ^ a b c d e f g h HIsarna: Game changer in the steel industry (PDF), Tata Steel, December 2017
  5. ^ a b Project voor duurzame staalproductie kan CO2-uitstoot met de helft terugdringen, Financieel Dagblad, 5 September 2018
  6. ^ a b van Boggelen, JWK; Meijer, HKA; Zeilstra, C; Hage, H; Broersen, P (26 September 2018). Hisarna - Demonstrating Low CO2 Ironmaking at Pilot scale. SteelVIA 2018. Dubai.
  7. ^ "ULCOS: Ultra-low carbon dioxide steelmaking". European Commission. Retrieved 17 March 2016.
  8. ^ a b "HIsarna". Retrieved 19 March 2016.
  9. ^ "HIsmelt process". Rio Tinto. Retrieved 19 March 2016.
  10. ^ a b c "HIsarna smelter technology". ULCOS. Retrieved 25 September 2010.
  11. ^ a b c "Belangrijke stap in Corus' CO2-project HISARNA" (in Dutch). Tata Steel Netherlands. 27 August 2010. Archived from the original on 3 April 2015. Retrieved 25 September 2010.
  12. ^ Shatokha, Volodymyr (2016), "Environmental Sustainability of the Iron and Steel Industry: Towards Reaching the Climate Goals", European Journal of Sustainable Development, vol. 5, pp. 289–300, doi:10.14207/ejsd.2016.v5n4p289
  13. ^ "Tata Steel strengthens position in low carbon future technology". Tata Steel. Retrieved 8 June 2018.
  14. ^ Koen Meijer; et al. (2015). Hisarna experimental campaigns B and C (HISARNA B and C). European Commission. ISBN 978-92-79-52718-0.
  15. ^ Breakthrough steelmaking technology to dramatically reduce CO2 emissions enters final testing, Tata Steel, archived from the original on 12 June 2018, retrieved 8 June 2018
  16. ^ Hebben de hoogovens van IJmuiden nog toekomst (in Dutch), ArvoTros, 20 October 2017, retrieved 8 June 2018
  17. ^ "EU-subsidie voor duurtest nieuw proces ruwijzerproductie" (in Dutch). Tata Steel. Retrieved 19 March 2016.
  18. ^ "Development of a Low CO2 Iron and Steelmaking Integrated Process Route for a Sustainable European Steel Industry". European Commission. Retrieved 19 March 2016.
  19. ^ "Tata kan verder met proef CO2-sparende ijzerproductie" (in Dutch). De Ingenieur. 1 July 2015. Retrieved 19 March 2016.
  20. ^ EP patent 0726326, Den Huibert Willem Hartog, Hendrikus Koenraad Albertus Meijer, "Method for producing molten pig iron", published 1996-08-14, issued 2001-11-07 
  21. ^ Jan van der Stel (28 November 2013). Gruene und nachhaltige Roheisenerzeugung mit Gichtgasrueckfuehrung beim Hochofen und HIsarna Schmelzreduktion (PDF). Stahl 2013 - Stahl in Bewegung. Duesseldorf: VDEh-Stahl. Archived from the original (PDF) on 5 March 2021. Retrieved 19 March 2016.
  22. ^ a b c van der Stel, Jan; Meijer, Koen; Santos, Stanley; Peeters, Tim; Broersen, Pieter (15 November 2017), HIsarna, an opportunity to reduce CO2 emissions from steel industry, CATO, retrieved 5 June 2018
  23. ^ J W K van Boggelen; H K A Meijer; C Zeilstra; Z Li (12 June 2016). The use of HIsarna hot metal in steelmaking. SCANMET V. Lulea, Sweden: SWEREA-MEFOS.
  24. ^ ReclaMet, EIT RawMaterials, retrieved 15 June 2018
  25. ^ IJmuiden grijpt naast nieuwe milieuvriendelijke staalfabriek, De Volkskrant, retrieved 1 December 2018
  26. ^ Tata Steel kiest onverwacht niet voor IJmuiden om nieuwe fabriek te vestigen, NHNieuws, retrieved 1 December 2018
  27. ^ IJMUIDEN ZIET CO2-ZUINIG STAALPROCES NAAR INDIA VERTREKKEN, De Ingenieur, retrieved 1 December 2018
  28. ^ Tata’s HIsarna naar India: zo zit het, processcontrol, retrieved 1 December 2018
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