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Hypoiodous acid

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Hypoiodous acid
Names
IUPAC name
Hypoiodous acid
Other names
Hypoiodous acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
  • InChI=1S/HIO/c1-2/h2H checkY
    Key: GEOVEUCEIQCBKH-UHFFFAOYSA-N checkY
  • HIO
Properties
HIO
Molar mass 143.89 g/mol
Appearance ?
Density ?
Melting point ?
Boiling point ?
?
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Hypoiodous acid (HIO) is formed when mercury(II) oxide is shaken with aqueous iodine.[1] It rapidly decomposes by disproportionation:[1]

5HIO → HIO3 + 2I2 + 2H2O

Reactive solutions of hypoiodites (salts of hypoiodous acid) can be prepared by reacting I2 with alkali hydroxides.[1]. They rapidly disproportionate to form iodides and iodates.[1]

In theory, HIO should be a powerful disinfectant as it is the iodine analogue to the hypochlorous acid formed when mixing chlorine with water. HIO is likely the active ingredient responsible for disinfection by iodine solutions used in the medical profession such as betadine or povidone iodine.[citation needed]

References

  1. ^ a b c d Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5