Hypoiodous acid

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Hypoiodous acid
Names
IUPAC name
Hypoiodous acid
Other names
Hypoiodous acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
  • InChI=1S/HIO/c1-2/h2H checkY
    Key: GEOVEUCEIQCBKH-UHFFFAOYSA-N checkY
  • HIO
Properties
HIO
Molar mass 143.89 g/mol
Appearance ?
Density ?
Melting point ?
Boiling point ?
?
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Hypoiodous acid is the inorganic compound with the chemical formula HIO. It forms when an aqueous solution of iodine is treated with mercuric or silver salts. It rapidly decomposes by disproportionation:[1]

5 HIO → HIO3 + 2I2 + 2H2O

Hypoiodous acid is a weak acid with a Ka of about 10−11. The conjugate base is hypoiodite (OI-). Salts of this anion can be prepared by treating I2 with alkali hydroxides. They rapidly disproportionate to form iodides and iodates.[1]

References

  1. ^ a b Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5