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Kieserite

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Kieserite
Kieserite
General
CategorySulfate minerals
Formula
(repeating unit)
MgSO4·H2O
Strunz classification7.CB.05
Dana classification29.6.2.1
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
H-M symbol: (2/m)
Space groupC2/c
Unit cella = 7.51 Å, b = 7.61 Å
c = 6.92 Å; β = 116.17°; Z = 4
Identification
ColorColorless, grayish-white or yellowish
Crystal habitMassive, granular; rarely as pyramidal crystals
TwinningContact on {001}, polysynthetic about [110]
Cleavage{110} and {111} perfect
FractureUneven
TenacityFragile
Mohs scale hardness3.5
LusterVitreous to dull
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.57
Optical propertiesBiaxial (+)
Refractive indexnα = 1.520 nβ = 1.533 nγ = 1.584
Birefringenceδ = 0.064
2V angle55°
Dispersionr > v, moderate
SolubilityIn water
References[1][2][3]

Kieserite is the magnesium sulfate mineral (MgSO4·H2O) and is named after Dietrich Georg von Kieser (Jena, Germany 1862). It has a vitreous luster and it is colorless, grayish-white or yellowish. Its hardness is 3.5 and crystallizes in the monoclinic crystal system. Gunningite is the zinc member of the kieserite group of minerals.[4]

Occurrence

Kieserite commonly occurs in marine evaporites and rarely in volcanic environments as a sublimate. It occurs in association with halite, carnallite, polyhalite, anhydrite, boracite, sulfoborite, leonite, epsomite and celestine.[3]

Mars

In early 2005, Mars Express, a European Space Agency orbiter, discovered evidence of kieserite in patches of Valles Marineris (the largest canyon on Mars), along with gypsum and polyhydrated sulfates. This is direct evidence of Mars's watery past and augments similar discoveries made by the Mars Exploration Rover Opportunity in 2004.

Uses

It is used in the production of Epsom salt and as a fertilizer, the overall global annual usage in agriculture in the mid 1970s was 2.3 million tons.[5]

Crystal structure of kieserite

See also

References

  1. ^ Kieserite data on Webmineral
  2. ^ Kieserite on Mindat.org
  3. ^ a b Kieserite in the Handbook of Mineralogy
  4. ^ Kieserite group on Mindat
  5. ^ Industrial Inorganic Chemistry, Karl Heinz Büchel, Hans-Heinrich Moretto, Dietmar Werner, John Wiley & Sons, 2nd edition, 2000, ISBN 9783527613335