Propylamine
Appearance
Names | |
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IUPAC name
Propan-1-amine[1]
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Other names
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Identifiers | |
3D model (JSmol)
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1098243 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.003.149 |
EC Number |
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1529 | |
PubChem CID
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RTECS number |
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UN number | 1277 |
CompTox Dashboard (EPA)
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Properties | |
C3H9N | |
Molar mass | 59.112 g·mol−1 |
Appearance | Colorless liquid |
Odor | fishy, ammoniacal |
Density | 719 mg mL−1 |
Melting point | −83.00 °C; −117.40 °F; 190.15 K |
Boiling point | 47 to 51 °C; 116 to 124 °F; 320 to 324 K |
Miscible | |
log P | 0.547 |
Vapor pressure | 33.01 kPa (at 20 °C) |
Henry's law
constant (kH) |
660 μmol Pa−1 kg−1 |
Acidity (pKa) | 10.71 |
Refractive index (nD)
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1.388 |
Thermochemistry | |
Heat capacity (C)
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162.51 J K−1 mol−1 |
Std molar
entropy (S⦵298) |
227.44 J K−1 mol−1 |
Std enthalpy of
formation (ΔfH⦵298) |
−101.9–−101.1 kJ mol−1 |
Std enthalpy of
combustion (ΔcH⦵298) |
−2.368–−2.362 MJ mol−1 |
Hazards | |
GHS labelling: | |
Danger | |
H225, H302, H311, H314, H331 | |
P210, P261, P280, P305+P351+P338, P310 | |
Flash point | −30 °C (−22 °F; 243 K) |
Explosive limits | 2–10.4% |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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Related compounds | |
Related alkanamines
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Propylamine, also known as n-propylamine, is an amine with the chemical formula C2H5CH2NH2 (also written as C3H7NH2 and C3H9N).
Propylamine is a weak base with its Kb (base dissociation constant) equaling 4.7 × 10−4.
Preparation
Propyl amine hydrochloride can be prepared by reacting 1-propanol with ammonium chloride in water at high temperature and pressure using a Lewis acid catalyst such as ferric chloride.
References
- ^ "Propylamine - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 26 March 2005. Identification and Related Records. Retrieved 4 May 2012.