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Topaz

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Topaz
180xp
A group of topaz crystals on matrix
General
CategorySilicate mineral
Formula
(repeating unit)
Al2SiO4(F,OH)2
Strunz classification9.AF.35
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPbnm
Unit cella = 4.65 Å, b = 8.8 Å,
c = 8.4 Å; Z = 4
Identification
ColorColorless (if no impurities), blue, brown, orange, gray, yellow, green, pink and reddish pink
Crystal habitPrismatic crystals with faces striated parallel to long dimension; also columnar, compact, massive
Cleavage[001] Perfect
FractureSubconchoidal to uneven
Mohs scale hardness8 (defining mineral)
LusterVitreous
StreakWhite
DiaphaneityTransparent
Specific gravity3.49–3.57
Optical propertiesBiaxial (+)
Refractive indexnα = 1.606–1.629
nβ = 1.609–1.631
nγ = 1.616–1.638
Birefringenceδ = 0.010
PleochroismWeak in thick sections X = yellow; Y = yellow, violet, reddish; Z = violet, bluish, yellow, pink
Ultraviolet fluorescenceShort UV=golden yellow; Long UV=cream
References[1][2][3][4]

Topaz is a silicate mineral of aluminium and fluorine with the chemical formula Al2SiO4(F,OH)2. Topaz crystallizes in the orthorhombic system, and its crystals are mostly prismatic terminated by pyramidal and other faces.

Color and varieties

Facet cut topaz gemstones in various colors
Yellow topaz in stepped kite-shaped cut

Pure topaz is colorless and transparent but is usually tinted by impurities; typical topaz is wine red, yellow, pale gray, reddish-orange, or blue brown. It can also be white, pale green, blue, gold, pink (rare), reddish-yellow or opaque to transparent/translucent.

Orange topaz, also known as precious topaz, is the traditional November birthstone, the symbol of friendship, and the state gemstone of the US state of Utah.[5]

Imperial topaz is yellow, pink (rare, if natural) or pink-orange. Brazilian Imperial Topaz can often have a bright yellow to deep golden brown hue, sometimes even violet. Many brown or pale topazes are treated to make them bright yellow, gold, pink or violet colored. Some imperial topaz stones can fade on exposure to sunlight for an extended period of time.[6][7]

Blue topaz is the state gemstone of the US state of Texas.[8] Naturally occurring blue topaz is quite rare. Typically, colorless, gray or pale yellow and blue material is heat treated and irradiated to produce a more desired darker blue.[7]

Mystic topaz is colorless topaz which has been artificially coated giving it the desired rainbow effect.[9]

Localities and occurrence

Topaz is commonly associated with silicic igneous rocks of the granite and rhyolite type. It typically crystallizes in granitic pegmatites or in vapor cavities in rhyolite lava flows including those at Topaz Mountain in western Utah and Chivinar in South America. It can be found with fluorite and cassiterite in various areas including the Ural and Ilmen mountains of Russia, in Afghanistan, Sri Lanka, Czech Republic, Germany, Norway, Pakistan, Italy, Sweden, Japan, Brazil, Mexico; Flinders Island, Australia; Nigeria and the United States.

Brazil is one of the largest producers of topaz,[10] some clear topaz crystals from Brazilian pegmatites can reach boulder size and weigh hundreds of pounds. Crystals of this size may be seen in museum collections. The Topaz of Aurangzeb, observed by Jean Baptiste Tavernier weighed 157.75 carats.[11] The American Golden Topaz, a more recent gem, weighed a massive 22,892.5 carats.

Colorless and light-blue varieties of topaz are found in Precambrian granite in Mason County, Texas[12] within the Llano Uplift. There is no commercial mining of topaz in that area.[13]

Etymology

The name "topaz" is usually derived (via Old French: Topace and Latin: Topazus) from the Greek Τοπάζιος (Τοpáziοs) or Τοπάζιον (Τοpáziοn),[14] from Τοπαζος, the ancient name of St. John's Island in the Red Sea which was difficult to find and from which a yellow stone (now believed to be chrysolite: yellowish olivine) was mined in ancient times; topaz itself (rather than topazios) was not really known before the classical era. Pliny said that Topazos is a legendary island in the Red Sea and the mineral "topaz" was first mined there. Alternatively, the word topaz may be related to the Sanskrit word तपस् "tapas", meaning "heat" or "fire".[14]

Historical usage

Nicols, the author of one of the first systematic treatises on minerals and gemstones, dedicated two chapters to the topic in 1652.[15] In the Middle Ages, the name topaz was used to refer to any yellow gemstone, but in modern times it denotes only the silicate described above.

Many modern English translations of the Bible, including the King James Version mention topaz. However, because these translations as topaz all derive from the Septuagint translation topazi[os], which as mentioned above referred to a yellow stone that was not topaz, but probably chrysolite (chrysoberyl or peridot), it should be borne in mind that topaz is likely not meant here.[16] The masoretic text (the Hebrew on which most modern Protestant Bible translations of the Old Testament are based) has pitdah as the gem the stone is made from; some scholars think it is related to an Assyrian word meaning "flashed".[citation needed] More likely, "pitdah" is derived from Sanskrit words (पीत pit = yellow, दह् dah = burn), meaning "yellow burn" or, metaphorically, "fiery"[citation needed].

Superstition

An English superstition held that topaz cured lunacy.[17]

References

  1. ^ Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., ISBN 0-471-80580-7
  2. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1995). "Topaz". Handbook of Mineralogy (PDF). Vol. II (Silica, Silicates). Chantilly, VA, US: Mineralogical Society of America. ISBN 978-0-9622097-1-0. Retrieved December 5, 2011.
  3. ^ Topaz. Mindat.org. Retrieved on 2011-10-29.
  4. ^ Topaz. Webmineral.com. Retrieved on 2011-10-29.
  5. ^ Utah State Gem – Topaz. Pioneer.utah.gov (2010-06-16). Retrieved on 2011-10-29.
  6. ^ Imperial Topaz, Natural History Museum of Los Angeles County
  7. ^ a b Gemstones & Gemology – Topaz, Emporia State University
  8. ^ State Gem – Texas Blue Topaz. State Gemstone Cut – Lone Star Cut. state.tx.us
  9. ^ Mystic Topaz, Consumer Information. Farlang.com (2008-10-30). Retrieved on 2011-10-29.
  10. ^ "Topaz Guide". Ayana Jewellery. Retrieved November 23, 2016.
  11. ^ Famous and Notheworthy Topazes Rao Bahadur, A Handbook of Precious Stones, Geological Survey of India
  12. ^ Handbook of Texas Online – Mineral Resources and Mining. Tshaonline.org. Retrieved on 2011-10-29.
  13. ^ Mason, Texas Chamber of Commerce Web site
  14. ^ a b Harper, Douglas. "topaz". Online Etymology Dictionary.
  15. ^ A Lapidary or History of Gemstones, University of Cambridge, 1652.
  16. ^ See for extensive discussion Oliver Farrington, Gems and Gem Minerals, Chicago, 1903, p. 119. Farrington was curator of Natural History Museum in Chicago.
  17. ^ On Superstitions Connected with the History and Practice of Medicine and Surgery by Thomas Joseph Pettigrew p.70, 1844